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Fe3O4/AC@SiO2@EDTA Manyetik Nano-Adsorbentin Sentezlenmesi ve Toluenin Gaz Adsorpsiyonunda Kullanılması

Year 2020, , 561 - 572, 15.06.2020
https://doi.org/10.17798/bitlisfen.602004

Abstract

Bu çevreci
çalışma, daha derin bir bakış açısı kazandırmakla mevcut çesitli benzen
adsorbsiyonu teknolojijisine katkı sunmaktadır. Bu çalışmada, hayati risk
oluşturan benzenin adsorpsiyonu için nano-teknolojiden faydalanmıştır.
Etilendiamin tetraasetik asit (EDTA) daha önce direkt Fe3O4’e
bağlanmış olsa da bu çalışma da Fe3O4, önce aktif
karbonla, sonra SiO2 ile daha sonra da EDTA ile kaplanmış,
böylelikle benzen adorbsiyonu için sentezi çok basit ve adsorbsiyon kapasitesi
pek iyi, literatürde rastlanmayan nano manyetik adsorbent sentezlenmiş,
sentezlenen bu nano manyetik adsorbent toluen adsorbsiyonunda başarılı ve
verimli bir şekilde uygulanmıştır. Toluenin gaz adsorpsiyonunda kullanılan
manyetik nano-adsorbent, birlikte çökeltme ve sol-gel yöntemiyle sentezlendi. Sentezlenen
manyetik nano-adsorbentin karakterizasyonu ise FTIR ve TGA/DTA analizleri ile
gerçekleştirilmiştir. Adsorpsiyon işleminde önemli bir rol oynayan adsorpsiyon
süresi, girişteki toluen konsantrasyonu ve adsorpsiyon sıcaklığı gibi adsorpsiyon
koşulları, Merkezi Kompozit Tasarım (MKT) yaklaşımı temelli Yanıt Yüzey Yöntemi
(YYY) kullanılarak optimize edilmiştir. Deneysel tasarımda, MKT ve YYY,
adsorpsiyon koşulları ile adsorpsiyon kapasitesi arasındaki ilişkiyi daha iyi
anlamak için bir yaklaşım geliştirmek üzere başarıyla uygulanmıştır. MKT ve YYY
kullanılarak bulunan 53.36 dk adsorpsiyon süresi, 18.02 ppm başlangıç
konsantrasyonu ve 26.21
°C adsorpsiyon sıcaklığı
gibi optimum adsorpsiyon koşulları altında, toluen için maksimum adsorpsiyon
kapasitesi 484.16 mg/g olarak belirlenmiştir.
Sonuçlar, manyetik Fe3O4/AC@SiO2@EDTA
nanopartiküllerinin, toluenin gaz adsorpsiyonunda
uygulanabileceğini göstermiştir.

References

  • 1. Maham M, Nasrollahzadeh M, Sajadi SM, Nekoei M. 2017. Biosynthesis of Ag/reduced graphene oxide/Fe3O4 using Lotus garcinii leaf extract and its application as a recyclable nanocatalyst for the reduction of 4-nitrophenol and organic dyes. Journal of colloid and interface science 497:33-42
  • 2. Abdollahi F, Pirisedigh A, Abbasinazari M, Mohammad–Alizadeh A, Azizian H. 2016. Synthesis of novel amino-coated Fe3O4 magnetic nanoparticle functionalized with ciprofloxacin (AF-Fe3O4-NP@ cpf) and study of its effect on Cu (II) and Ni (II) adsorption. Iranian Journal of Pharmacology and Therapeutics 14:50-0
  • 3. Dung DTK, Hai TH, Long BD, Truc PN. Preparation and characterization of magnetic nanoparticles with chitosan coating. Proc. Journal of Physics: Conference Series, 2009, 187:012036: IOP Publishing
  • 4. Wu Q, Zhao R, Liu W, Zhang X, Shen X, et al. 2017. In-depth nanocrystallization enhanced Li-ions batteries performance with nitrogen-doped carbon coated Fe3O4 yolk− shell nanocapsules. Journal of Power Sources 344:74-84
  • 5. Baby TT, Ramaprabhu S. 2010. SiO2 coated Fe3O4 magnetic nanoparticle dispersed multiwalled carbon nanotubes based amperometric glucose biosensor. Talanta 80:2016-22
  • 6. Yang K, Peng H, Wen Y, Li N. 2010. Re-examination of characteristic FTIR spectrum of secondary layer in bilayer oleic acid-coated Fe3O4 nanoparticles. Applied surface science 256:3093-7
  • 7. Kumar M, Giri BS, Kim K-H, Singh RP, Rene ER, et al. 2019. Performance of a biofilter with compost and activated carbon based packing material for gas-phase toluene removal under extremely high loading rates. Bioresource technology 285:121317
  • 8. Ryu HW, Song MY, Park JS, Kim JM, Jung S-C, et al. 2019. Removal of toluene using ozone at room temperature over mesoporous Mn/Al2O3 catalysts. Environmental research 172:649-57
  • 9. Xu P, Wei Y, Cheng N, Li S, Li W, et al. 2019. Evaluation on the removal performance of dichloromethane and toluene from waste gases using an airlift packing reactor. Journal of hazardous materials 366:105-13
  • 10. Ghelich R, Jahannama MR, Abdizadeh H, Torknik FS, Vaezi MR. 2019. Central composite design (CCD)-Response surface methodology (RSM) of effective electrospinning parameters on PVP-B-Hf hybrid nanofibrous composites for synthesis of HfB2-based composite nanofibers. Composites Part B: Engineering 166:527-41
  • 11. Qu S, Wang J, Kong J, Yang P, Chen G. 2007. Magnetic loading of carbon nanotube/nano-Fe3O4 composite for electrochemical sensing. Talanta 71:1096-102
  • 12. Tural S, Ece MŞ, Tural B. 2018. Synthesis of novel magnetic nano-sorbent functionalized with N-methyl-D-glucamine by click chemistry and removal of boron with magnetic separation method. Ecotoxicology and environmental safety 162:245-52
  • 13. Mostafalu R, Kaboudin B, Kazemi F, Yokomatsu T. 2014. N-arylation of amines: C–N coupling of amines with arylboronic acids using Fe 3 O 4 magnetic nanoparticles-supported EDTA–Cu (ii) complex in water. RSC Advances 4:49273-9
  • 14. Kutluay S, Baytar O, Şahin Ö. 2019. Equilibrium, kinetic and thermodynamic studies for dynamic adsorption of benzene in gas phase onto activated carbon produced from elaeagnus angustifolia seeds. Journal of Environmental Chemical Engineering 7:102947
  • 15. Pimenta CD, Silva MB, de Morais Campos RL, de Campos Junior WR. 2018. Desirability and design of experiments applied to the optimization of the reduction of decarburization of the process heat treatment for steel wire SAE 51B35. American Journal of Theoretical and Applied Statistics 7:35-44
Year 2020, , 561 - 572, 15.06.2020
https://doi.org/10.17798/bitlisfen.602004

Abstract

References

  • 1. Maham M, Nasrollahzadeh M, Sajadi SM, Nekoei M. 2017. Biosynthesis of Ag/reduced graphene oxide/Fe3O4 using Lotus garcinii leaf extract and its application as a recyclable nanocatalyst for the reduction of 4-nitrophenol and organic dyes. Journal of colloid and interface science 497:33-42
  • 2. Abdollahi F, Pirisedigh A, Abbasinazari M, Mohammad–Alizadeh A, Azizian H. 2016. Synthesis of novel amino-coated Fe3O4 magnetic nanoparticle functionalized with ciprofloxacin (AF-Fe3O4-NP@ cpf) and study of its effect on Cu (II) and Ni (II) adsorption. Iranian Journal of Pharmacology and Therapeutics 14:50-0
  • 3. Dung DTK, Hai TH, Long BD, Truc PN. Preparation and characterization of magnetic nanoparticles with chitosan coating. Proc. Journal of Physics: Conference Series, 2009, 187:012036: IOP Publishing
  • 4. Wu Q, Zhao R, Liu W, Zhang X, Shen X, et al. 2017. In-depth nanocrystallization enhanced Li-ions batteries performance with nitrogen-doped carbon coated Fe3O4 yolk− shell nanocapsules. Journal of Power Sources 344:74-84
  • 5. Baby TT, Ramaprabhu S. 2010. SiO2 coated Fe3O4 magnetic nanoparticle dispersed multiwalled carbon nanotubes based amperometric glucose biosensor. Talanta 80:2016-22
  • 6. Yang K, Peng H, Wen Y, Li N. 2010. Re-examination of characteristic FTIR spectrum of secondary layer in bilayer oleic acid-coated Fe3O4 nanoparticles. Applied surface science 256:3093-7
  • 7. Kumar M, Giri BS, Kim K-H, Singh RP, Rene ER, et al. 2019. Performance of a biofilter with compost and activated carbon based packing material for gas-phase toluene removal under extremely high loading rates. Bioresource technology 285:121317
  • 8. Ryu HW, Song MY, Park JS, Kim JM, Jung S-C, et al. 2019. Removal of toluene using ozone at room temperature over mesoporous Mn/Al2O3 catalysts. Environmental research 172:649-57
  • 9. Xu P, Wei Y, Cheng N, Li S, Li W, et al. 2019. Evaluation on the removal performance of dichloromethane and toluene from waste gases using an airlift packing reactor. Journal of hazardous materials 366:105-13
  • 10. Ghelich R, Jahannama MR, Abdizadeh H, Torknik FS, Vaezi MR. 2019. Central composite design (CCD)-Response surface methodology (RSM) of effective electrospinning parameters on PVP-B-Hf hybrid nanofibrous composites for synthesis of HfB2-based composite nanofibers. Composites Part B: Engineering 166:527-41
  • 11. Qu S, Wang J, Kong J, Yang P, Chen G. 2007. Magnetic loading of carbon nanotube/nano-Fe3O4 composite for electrochemical sensing. Talanta 71:1096-102
  • 12. Tural S, Ece MŞ, Tural B. 2018. Synthesis of novel magnetic nano-sorbent functionalized with N-methyl-D-glucamine by click chemistry and removal of boron with magnetic separation method. Ecotoxicology and environmental safety 162:245-52
  • 13. Mostafalu R, Kaboudin B, Kazemi F, Yokomatsu T. 2014. N-arylation of amines: C–N coupling of amines with arylboronic acids using Fe 3 O 4 magnetic nanoparticles-supported EDTA–Cu (ii) complex in water. RSC Advances 4:49273-9
  • 14. Kutluay S, Baytar O, Şahin Ö. 2019. Equilibrium, kinetic and thermodynamic studies for dynamic adsorption of benzene in gas phase onto activated carbon produced from elaeagnus angustifolia seeds. Journal of Environmental Chemical Engineering 7:102947
  • 15. Pimenta CD, Silva MB, de Morais Campos RL, de Campos Junior WR. 2018. Desirability and design of experiments applied to the optimization of the reduction of decarburization of the process heat treatment for steel wire SAE 51B35. American Journal of Theoretical and Applied Statistics 7:35-44
There are 15 citations in total.

Details

Primary Language Turkish
Journal Section Araştırma Makalesi
Authors

Mehmet Şakir Ece 0000-0002-9411-314X

Publication Date June 15, 2020
Submission Date August 5, 2019
Acceptance Date December 6, 2019
Published in Issue Year 2020

Cite

IEEE M. Ş. Ece, “Fe3O4/AC@SiO2@EDTA Manyetik Nano-Adsorbentin Sentezlenmesi ve Toluenin Gaz Adsorpsiyonunda Kullanılması”, Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, vol. 9, no. 2, pp. 561–572, 2020, doi: 10.17798/bitlisfen.602004.



Bitlis Eren Üniversitesi
Fen Bilimleri Dergisi Editörlüğü

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E-posta: fbe@beu.edu.tr