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Boric Acid Production From Sodium Metaborate With Sulfuric Acid

Year 2015, Volume: 11 Issue: 3, 0 - , 23.12.2015

Hilal Demirel Taylan İnce Duygu Uysal Bekir Uysal

https://doi.org/10.18466/cbujos.22763
Cited By: 1

Abstract

In this study, boric acid production with aqueous phase reaction of sodium metaborate with sulfuric acid is investigated. Sodium metaborate is the byproduct of catalytic hydrolysis of sodium borohydride reaction. It was reacted batchwise at 90oC for 30 minutes with 98% H2SO4 solution. After the boric acid production, purification was investigated using ethanol, acetone and saturated boric acid solution. 97.78%, 93.13% and 100% pure boric acid products were obtained, respectively. These results, supported by XRD analysis, indicate that the proposed method was successful and it is possible to produce boric acid by reacting sodium metaborate directly with sulfuric acid.

Keywords

sodium metaborate; boric acid; sodium borohydride

References

  • http://www.etimaden.gov.tr/borik-asit-113s.htm , 02.07.2015
  • Newman, A. 1932. Process of preparing boric Acid. ABD Patent (1,888,391).
  • Taylor, D. S. 1953. Production and seperation of anhydrous alkali metal sulfate and boric acid. ABD Patenti (2,637,626)
  • Taylor, D. S. 1956. Production of boric acid and anhydrous sodium sulfate, ABD Patenti (2,746,841).
  • Bedri, D. E. & Tolun, R. 1979. Boric Acid and Sodium Sulphate Produciton from Tincale ,Tubitak Report .
  • Boric Acid Production from Tincal, A. Mergen, H. Demirhan, M. Bilen, H. Cebi & M, Gündüz Eti Holding A.Ş., Directorate of Ress.&Dev. Department, Ankara, TURKEY, 2001.
  • http://www.boren.gov.tr/tr/projeler/proje-ciktilari/uretim-ve-uygulama-teknolojisi-gelistirilen-urunler, 14.07.2015
  • İ. Kayacan, Ö. M. Dogan, B. Z. Uysal, Int Jr of Hydrogen Energy, 2011, 36 (13), 7410-7415.
  • Gögce, Ö. Ö, U. G. Zafer, B. Z. Uysal, Proceedings of 4th Intn. Boron Symposium, 2009, Ed. A. Konuk et al., Eskişehir, 267-271.
  • Schlesinger, H. I., H. C. Brown, A. E. Finhold, Jr of American Chemical Society, 1953, 75, 205-209.
  • Product Data Sheet Sodium Metaborate 8 Mol, 20 Mule Team Borax.
  • Product Data Sheet Optibor Boric Acids, 20 Mule Team Borax.
  • Perry, R . Perry's Chemical Engineers' Handbook, 6th edition, McGraw-Hill Book Company,1984.

Year 2015, Volume: 11 Issue: 3, 0 - , 23.12.2015

Hilal Demirel Taylan İnce Duygu Uysal Bekir Uysal

https://doi.org/10.18466/cbujos.22763
Cited By: 1

Abstract

References

  • http://www.etimaden.gov.tr/borik-asit-113s.htm , 02.07.2015
  • Newman, A. 1932. Process of preparing boric Acid. ABD Patent (1,888,391).
  • Taylor, D. S. 1953. Production and seperation of anhydrous alkali metal sulfate and boric acid. ABD Patenti (2,637,626)
  • Taylor, D. S. 1956. Production of boric acid and anhydrous sodium sulfate, ABD Patenti (2,746,841).
  • Bedri, D. E. & Tolun, R. 1979. Boric Acid and Sodium Sulphate Produciton from Tincale ,Tubitak Report .
  • Boric Acid Production from Tincal, A. Mergen, H. Demirhan, M. Bilen, H. Cebi & M, Gündüz Eti Holding A.Ş., Directorate of Ress.&Dev. Department, Ankara, TURKEY, 2001.
  • http://www.boren.gov.tr/tr/projeler/proje-ciktilari/uretim-ve-uygulama-teknolojisi-gelistirilen-urunler, 14.07.2015
  • İ. Kayacan, Ö. M. Dogan, B. Z. Uysal, Int Jr of Hydrogen Energy, 2011, 36 (13), 7410-7415.
  • Gögce, Ö. Ö, U. G. Zafer, B. Z. Uysal, Proceedings of 4th Intn. Boron Symposium, 2009, Ed. A. Konuk et al., Eskişehir, 267-271.
  • Schlesinger, H. I., H. C. Brown, A. E. Finhold, Jr of American Chemical Society, 1953, 75, 205-209.
  • Product Data Sheet Sodium Metaborate 8 Mol, 20 Mule Team Borax.
  • Product Data Sheet Optibor Boric Acids, 20 Mule Team Borax.
  • Perry, R . Perry's Chemical Engineers' Handbook, 6th edition, McGraw-Hill Book Company,1984.
There are 13 citations in total.

Details

Primary Language English
Journal Section Articles
Authors

Hilal Demirel This is me

Taylan İnce This is me

Duygu Uysal This is me

Bekir Uysal

Publication Date December 23, 2015
Published in Issue Year 2015 Volume: 11 Issue: 3

Cite

APA Demirel, H., İnce, T., Uysal, D., Uysal, B. (2015). Boric Acid Production From Sodium Metaborate With Sulfuric Acid. Celal Bayar University Journal of Science, 11(3). https://doi.org/10.18466/cbujos.22763
AMA Demirel H, İnce T, Uysal D, Uysal B. Boric Acid Production From Sodium Metaborate With Sulfuric Acid. CBUJOS. December 2015;11(3). doi:10.18466/cbujos.22763
Chicago Demirel, Hilal, Taylan İnce, Duygu Uysal, and Bekir Uysal. “Boric Acid Production From Sodium Metaborate With Sulfuric Acid”. Celal Bayar University Journal of Science 11, no. 3 (December 2015). https://doi.org/10.18466/cbujos.22763.
EndNote Demirel H, İnce T, Uysal D, Uysal B (December 1, 2015) Boric Acid Production From Sodium Metaborate With Sulfuric Acid. Celal Bayar University Journal of Science 11 3
IEEE H. Demirel, T. İnce, D. Uysal, and B. Uysal, “Boric Acid Production From Sodium Metaborate With Sulfuric Acid”, CBUJOS, vol. 11, no. 3, 2015, doi: 10.18466/cbujos.22763.
ISNAD Demirel, Hilal et al. “Boric Acid Production From Sodium Metaborate With Sulfuric Acid”. Celal Bayar University Journal of Science 11/3 (December 2015). https://doi.org/10.18466/cbujos.22763.
JAMA Demirel H, İnce T, Uysal D, Uysal B. Boric Acid Production From Sodium Metaborate With Sulfuric Acid. CBUJOS. 2015;11. doi:10.18466/cbujos.22763.
MLA Demirel, Hilal et al. “Boric Acid Production From Sodium Metaborate With Sulfuric Acid”. Celal Bayar University Journal of Science, vol. 11, no. 3, 2015, doi:10.18466/cbujos.22763.
Vancouver Demirel H, İnce T, Uysal D, Uysal B. Boric Acid Production From Sodium Metaborate With Sulfuric Acid. CBUJOS. 2015;11(3).

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