One-step preparation of silver nanoparticle containing polymer nanocomposites via stereolithography technique

Ayberk Baykal; Onur Alp Aksan; Ahmet Yavuz Oral; Kaan Bilge; Nuray Kızıldağ

doi:10.61112/jiens.1396859

Research Article

Sterolitografi tekniği ile tek adımda gümüş nanopartikül içeren nanokompozitlerin hazırlanması

Year 2024, Volume: 4 Issue: 2, 263 - 275

Ayberk Baykal Onur Alp Aksan Ahmet Yavuz Oral Kaan Bilge Nuray Kızıldağ

https://doi.org/10.61112/jiens.1396859

Abstract

As a technique that uses ultraviolet light to cure photo-polymers layer by layer with high spatial resolution and surface quality, stereolithography (SLA) allows for precise process control and optimization for various UV-curable polymers and their nanocomposites with various nanoparticles. In this study, UV-curable polymer nanocomposites were prepared with the addition of different contents of silver nitrate via SLA technique for use in antibacterial applications. In-situ synthesis of AgNPs was achieved during the SLA process without any additional treatments. The effect of AgNO3 addition on the curing of the resin and the mechanical properties of the nanocomposite specimens were investigated. To understand the fracture mechanism of the nanocomposite samples, the fractured surfaces of the samples were evaluated by SEM, and the AgNO3 content of the nanocomposite was evaluated by EDX. The nanocomposites containing 0.3 wt. % AgNO3 exhibited improved mechanical properties. Further increasing the AgNO3 content to 3 wt. % led to deterioration in the physical and mechanical properties of the polymer nanocomposites.

Keywords

Antibakteriyel, Mekanik özellikler, Polimer nanokompozitler, Fotopolimerizasyon, Gümüş nanopartiküller, Stereolitografi

Project Number

GTU-BAP Project 2023-A-101-15

References

Al Rashid A, Khan A, Al-Ghamdi SG, Koc M (2021) Additive manufacturing of polymer nanocomposites: Needs and challenges in materials, processes, and applications. Journal of Materials Research and Technology, 14:910-941. https://doi.org/10.1016/j.jmrt.2021.07.016
Wu H, Fahy WP, Kim S, Kim H, Zhao N, Pilato L, Kafi A, Bateman S, Koo JH (2020) Recent developments in polymers/polymer nanocomposites for additive manufacturing. Progress in Materials Science, 111: 100638. https://doi.org/10.1016/j.pmatsci.2020.100638
Ahangar P, Cooke ME, Weber MH, Rosenzweig DH (2019) Current biomedical applications of 3D printing and additive manufacturing. Applied Sciences, 9:1713. https://doi.org/10.3390/APP9081713
Nachal N, Moses JA, Karthik P, Anandharamakrishnan C (2019) Applications of 3D printing in food processing. Food Engineering Reviews 11:123–141. https://doi.org/10.1007/S12393-019-09199-8
Campbell TA, Ivanova OS (2013) 3D Printing of multifunctional nanocomposites. Nano Today, 8:119–120, https://doi.org/10.1016/j.nantod.2012.12.002
Taormina G, Sciancalpore C, Messori M, Bondioli F (2018) Advanced resins for stereolithography: In situ generation of silver nanoparticles. AIP Conference Proceedings, 1981:20065. https://doi.org/10.1063/1.5045927
Fantino E, Chiappone A, Roppolo I, Manfredi D, Bongiovanni R, Pirri CF, Calignano F (2016) 3D Printing of conductive complex structures with in situ generation of silver nanoparticles. Advanced Materials, 28(19):3712–3717. https://doi.org/10.1002/ADMA.201505109
Kartal I., Ozcan Z. (2023) Investigation of effect of chestnut sawdust on mechanical properties of epoxy matrix composites. Journal of Innovative Engineering and Natural Science, 3(2):67-74. https://doi.org/10.29228/JIENS.69363
Khalid MY, Imran R, Arif ZU, Akram N, Arshad H, Al Rashid A, Márquez FPG (2021) Developments in chemical treatments, manufacturing techniques and potential applications of natural-fibers-basedb biodegradable composites. Coatings, 11:293. https://doi.org/10.3390/COATINGS11030293
Billings C (2023) Additive manufacturing and synthesis of advanced antibacterial and sensing photocurable polymer nanocomposites. Dissertation, University of Oklahoma.
Sangermano M, Tagci Y, Rizza G (2007). In situ synthesis of silver-epoxy nanocomposites by photoinduced electron transfer and cationic polymerization processes. Macromolecules, 40:8827-8829. https://doi.org/10.1021/ma702051g
Peerzada M, Abbasi S, Lau KT, Hameed N (2020). Additive manufacturing of epoxy resins: Materials, methods, and latest trends. Industrial&Engineering Chemistry Research, 59(14):6375-6390. https://doi.org/10.1021/acs.iecr.9b06870
Bruna T, Maldonado-Bravo F, Jara P, Caro N (2021) Silver nanoparticles and their antibacterial applications. International Journal of Molecular Sciences, 22(13):7202. https://doi.org/10.3390/ijms22137202
Valencia LM, Herrera M, de la Mata M, de León AS, Delgado FJ, Molina SI (2022) Synthesis of silver nanocomposites for stereolithography: in situ formation of nanoparticles. Polymers, 14(6):1168. https://doi.org/10.3390/polym14061168
Yaragatti N, Patnaik A (2021) A review on additive manufacturing of polymers composites. Materials Today: Proceedings, 44:4150-4157. https://doi.org/10.1016/j.matpr.2020.10.490
Anastasio R, Peerbooms W, Cardinaels R, Van Breemen LCA (2019) Characterization of ultraviolet-cured methacrylate networks: From photopolymerization to ultimate mechanical properties. Macromolecules, 52:9220–9231. https://doi.org/10.1021/ACS.MACROMOL.9B01439
Singh N, Khyanna P (2007) In situ synthesis of silver nano-particles in polymethylmethacrylate. Materials Chemistry and Physics, 104 (2-3):367-372. https://doi.org/10.1016/j.matchemphys.2007.03.026
Darman Singho N, Akmal Che Lah N, Rafie Johan M, Ahmad R (2012) FTIR Studies on silver-poly(methylmethacrylate) nanocomposites via in-situ polymerization technique. International Journal of Electrochemical Science, 7(6):5596-5603. https://doi.org/10.1016/S1452-3981(23)19646-5
Siddiqui MN, Redhwi HH, Vakalopoulou E, Tsagkalias I, Ioannidou MD, Achilias DS (2015) Synthesis, characterization and reaction kinetics of PMMA/silver nanocomposites prepared via in situ radical polymerization. European Polymer Journal, 72:256–269. https://doi.org/10.1016/j.eurpolymj.2015.09.019
Russ, J. C. (1984) Fundamentals of Energy Dispersive X-ray Analysis, Butterworths, London.
https://www.edax.com/resources/posters/periodic-table-poster, accessed on 29.01.2024
Chinni, S. V., Gopinath, S. C., Anbu, P., Fuloria, N. K., Fuloria, S., Mariappan, P., ... & Samuggam, S. (2021). Characterization and antibacterial response of silver nanoparticles biosynthesized using an ethanolic extract of Coccinia indica leaves. Crystals, 11(2), 97. https://doi.org/10.3390/cryst11020097
Shaban, M., Ahmed, A., Abdel-Rahman, E., Hamdy, H. (2017) Tunability and Sensing Properties of Plasmonic/1D Photonic Crystal. Scientific Reports, 7, 41983. https://doi.org/10.1038/srep41983