Preparation and Characterization of Pvp Stabilized Rhodium Iron Bimetallic Nanoclusters and Investigation of Catalytic Activity in DMAB Hydrolysis

Year 2023, Volume: 13 Issue: 3, 1958 - 1969, 01.09.2023

Yaşar Karataş Adem Rüzgar

https://doi.org/10.21597/jist.1278345

Abstract

Rh-Fe nanoparticles (Rh-Fe@PVP) stabilized with poly(N-vinyl-2-pyrrolidone) (PVP) were synthesized by alcohol reduction technique, which is an efficient and environmentally friendly method. The synthesized nanoparticles were characterized by SEM, SEM/EDX, UV/Vis techniques. The prepared nanoparticles were used as a catalyst in the production of hydrogen from the hydrolysis reaction of dimethylamine-borane, a boron-nitrogen (B-N) derivative, which stands out due to its advantages such as high hydrogen content, stability and environmental friendliness. Bimetallic nanoparticles, which were calculated as TOF value (54.24 1/min) and activation energy (49.9 kJ/mol), were evaluated as an efficient catalytic system with these properties. As a result of investigating the effects of catalyst and substrate concentrations on the catalytic reaction, the rate expression of the reaction; It was determined that it progressed from 0.4 order according to the catalyst concentration and 0.3 order according to the substrate concentration.

Keywords

Energy, Hydrogen, Catalyst, PVP, DMAB

Pvp ile Kararlaştırılmış Rodyum Demir Bimetalik Nanokümelerinin Hazırlanması, Karakterizasyonu ve DMAB Hidrolizindeki Katalitik Etkinliğinin İncelenmesi

Abstract

Poli(N-vinil-2-pirolidon) (PVP) ile kararlaştırılmış Rh-Fe nanoparçacıkları (Rh-Fe@PVP) verimli ve çevreci bir yöntem olan alkol indirgeme tekniği ile sentezlendi. Sentezlenen nanoparçacıklar SEM, SEM/EDX, UV/Vis teknikleriyle karakterize edildi. Hazırlanan nanoparçacıklar yüksek hidrojen içeriği, kararlılığı ve çevre dostu olması gibi avantajları nedeniyle öne çıkan bir bor-azot (B-N) türevi olan dimetilamin-boranın hidroliz tepkimesinden hidrojen üretiminde katalizör olarak kullanıldı. TOF değeri (54.24 1/min) ve aktivasyon enerjisi (49.9 kJ/mol) olarak hesaplanan iki metalli nanoparçacıklar bu özellikleri ile verimli bir katalitik sistem olarak değerlendirildi. Katalizör ve substrat konsantrasyonlarının katalitik tepkime üzerindeki etkilerinin araştırılması sonucu tepkimenin hız ifadesinin; katalizör konsantrasyonuna göre 0.4 mertebeden, substrat konsantrasyonuna göre ise 0.3 mertebeden ilerlediği tespit edildi.

Keywords

Enerj, Hidrojen, Katalizör, PVP, DMAB

References

• Cai, H. K., Jiang, Z. Y., Xu, S., Xu, Y., Lu, P., Dong, J. (2022). Polymer Hydrogel Supported Ni/Pd Alloys for Hydrogen Gas Production from Hydrolysis of Dimethylamine Borane with a Long Recyclable Lifetime. Polymers, 14(21), 4647.
• Cai, H., Liu, L., Chen, Q., Lu, P., Dong J. (2016). Ni-polymer nanogel hybrid particles: A new strategy for hydrogen production from the hydrolysis of dimethylamine-borane and sodium borohydride. Energy, 99, 129-135.
• Çelebi, M., Rüzgar, A., Karataş, Y., Gülcan M. (2022). Manganese oxide octahedral molecular sieves stabilized Rh nanoparticles for the hydrogen production from the ethylenediamine-bisborane hydrolysis. Internatıonal Journal of Hydrogen Energy, 47(37),16494-16506
• Duan, Y., Guo, P., Sui, D., Deng, D., Lu, T., Yang, Y. (2022). Investigation on M@ CuOx/C (M= Ru, Rh, Pd and Pt) catalysts prepared by galvanic reduction for hydrogen evolution from ammonia borane. International Journal of Hydrogen Energy, 47(85), 36098-36109.
• Fukaume, S., Nagasaki, Y., Tsuda, M. (2022). Stable power supply of an independent power source for a remote island using a Hybrid Energy Storage System composed of electric and hydrogen energy storage systems. International Journal of Hydrogen Energy, 47(29), 13887-13899.
• Günbatar, S., Aygun, A., Karataş, Y., Gülcan, M., Şen F. (2018). Carbon-nanotube-based rhodium nanoparticles as highly-active catalyst for hydrolytic dehydrogenation of dimethylamineborane at room temperature. Journal of colloid and interface science, 530, 321-327.
• Jia, H., Liu, S., Zheng, G. P., Zheng, X. C., Wang, X. Y., Liu, P. (2019). Collagen-graphene oxide magnetic hybrids anchoring Pd (0) catalysts for efficient H2 generation from ammonia borane. International Journal of Hydrogen Energy, 44(49), 27022-27029.
• Kanat, M., Karataş, Y., Gülcan, M., Anıl, B. (2018). Preparation and detailed characterization of zirconia nanopowder supported rhodium (0) nanoparticles for hydrogen production from the methanolysis of methylamine-borane in room conditions. International Journal of Hydrogen Energy, 43(50), 22548-22556.
• Karaboğa, S. (2022). In situ prepared tungsten (VI) oxide supported Pd0 NPs, remarkable activity andreusability in H2 releasing from dimethylamine borane. Turkish Journal of Chemistry, 46(2), 394-403.
• Karaboga, S., Özkar, S. (2019). Nanoalumina supported palladium (0) nanoparticle catalyst for releasing H2 from dimethylamine borane. Applied Surface Science, 487, 433-441.
• Karahan, S., Zahmakıran, M., Özkar, S. (2011). Catalytic hydrolysis of hydrazine borane for chemical hydrogen storage: highly efficient and fast hydrogen generation system at room temperature. International Journal of Hydrogen Energy, 36(8), 4958-4966.
• Keskin M. S., Ağırtaş M. S., Baytar O., İzgi M. S., Şahin Ö. (2020). Potasyum Borhidrit Hidroliz Reaksiyonu İçin Ni-B-P Katalizörünün Kinetik Özellikleri, Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, c. 9, sayı. 2, ss. 599-608, Haz. 2020, doi:10.17798/bitlisfen.623941
• Li, B., Zhang, W., Huan, Y., Dong, J. (2018). Synthesis and characterization of Ni-B/Al2O3 nanocomposite coating by electrodeposition using trimethylamine borane as boron precursor. Surface and Coatings Technology, 337, 186-197. Liu, J., Li, P., Jiang, R., Zheng, X., Liu, P. (2021). Ru nanoparticles immobilized on chitosan as effective catalysts for boosting NH3BH3 hydrolysis. ChemCatChem, 13, 4142-415
• Lu, Z. H., Yao, Q., Zhang, Z., Yang, Y., Chen, X. (2014). Nanocatalysts for hydrogen generation from ammonia borane and hydrazine borane. Journal of Nanomaterials, 4,4.
• Nixon, T. D., Whittlesey, M. K., Williams, J. M. (2011). Ruthenium-catalysed transfer hydrogenation reactions with dimethylamine borane. Tetrahedron letters, 52(49), 6652-6654
• Onat E., Şahin Ö., İzgi M. S., Horoz S. (2021). An efficient synergistic Co@CQDs catalyst for hydrogen production from the hydrolysis of NH3BH3. Journal of Materials Science: Materials in Electronics. 32, 27251–27259
• Şen, B., Aygün, A., Şavk, A., Duman, S., Calimli, M. H., Bulut, E, Şen, F. (2019). Polymer-graphene hybrid stabilized ruthenium nanocatalysts for the dimethylamine-borane dehydrogenation at ambient conditions. Journal of Molecular Liquids, 279, 578-583.
• Shen, J., Yang, L., Hu, K., Luo, W., Cheng, G. (2015). Rh nanoparticles supported on graphene as efficient catalyst for hydrolytic dehydrogenation of amine boranes for chemical hydrogen storage. International Journal of Hydrogen Energy, 40(2), 1062-1070.
• Sogut, E. G., Acidereli, H., Kuyuldar, E., Karatas, Y., Gulcan, M., Sen, F. (2019). Single-walled carbon nanotube supported Pt-Ru bimetallic superb nanocatalyst for the hydrogen generation from the methanolysis of methylamine-borane at mild conditions. Scientific Reports, 9(1), 1-9.
• Umegaki, T., Yan, J. M., Zhang, X. B., Shioyama, H., Kuriyama, N., Xu, Q. (2009). Preparation and catalysis of poly(N-vinyl-2-pyrrolidone) (PVP) stabilized nickel catalyst for hydrolytic dehydrogenation of ammonia borane. International Journal of Hydrogen Energy 34( 9), 3816-3822
• Wei, Q., Liu, J., Qiu, S., Xia, Y., Zou, Y., Xu, F., Wen, X., Huang, P., Sun, L., Chu, H. (2022). Hydrogen Evolution from Ammonia–Borane Hydrolysis Catalyzed by Poly(N-Vinyl-2-Pyrrolidone)-Stabilized Ruthenium-Based Nanoclusters Catalysts. Adv. Sustainable Syst. 2200464
• Wen, Z., Fu, Q., Wu, J., Fan, G. (2020). Ultrafine Pd nanoparticles supported on soft nitriding porous carbon for hydrogen production from hydrolytic dehydrogenation of dimethyl amine-borane. Nanomaterials, 10(8), 1612.
• Wu, D., Wang, D., Ramachandran, T., & Holladay, J. (2022). A techno-economic assessment framework for hydrogen energy storage toward multiple energy delivery pathways and grid services. Energy, 249, 123638.
• Xu, F., Liu, X. (2021). Synergistically promoted H2 evolution from dimethylamine-borane and hydrazine monohydrate by simply alloying of Pt/C with Ni. Fuel, 304, 121433
• Yıldırım, R., Gülcan, M. (2021). H2 production from the hydrolytic dehydrogenation of methylamine-borane catalyzed by sulfonated reduced graphene oxide-aided synthesis of ruthenium nanoparticles. International Journal of Hydrogen Energy, 46(64), 32523-32535.
• Zeng, Y. F., Li, Y. N., Zhou, M. X., Han, S., Guo, Y., Wang, Z. (2022). Metal‐Free Hydrogenation of N‐Heterocycles with Trimethylamine Borane and TFA in Aqueous Solution. Advanced Synthesis & Catalysis, 364(21), 3664-3669.
• Zhou, J., Meng, X., Yan, J., Liu, X. (2021). Co/MoS2 nanocomposite catalyzed H2 evolution upon dimethylamine-borane hydrolysis and in situ tandem reaction. Inorganic Chemistry Communications, 130, 108691