Synthesis of Imino Stabilized Iron Oxide Nanosensor for Selective Detection of Lead Ions

Year 2023, , 277 - 286, 31.05.2023

Erum Hasan Syed Alı Ambreen Zia Sabira Begum Salman Tariq Khan Syeda Bukhari

https://doi.org/10.18596/jotcsa.1097197

Abstract

The present work describes the successful preparation of iron oxide nanoparticles (NSB1) stabilized with 4-((2-hydroxybenzylidene)amino)benzoic acid. The characterization has been achieved through ultraviolet visible (UV-Vis), fourier transform infra-red (FTIR) spectroscopy and scanning electron microscopy (SEM) with electron dispersive X-ray elemental analysis (EDX). These magnetic nanoparticles have exhibited significant chemosensing properties in the aqueous media to screen Cr3+, Cd2+, Li+, Co2+, Al3+, Pb2+, Ni2+ and Sr2+ ions. However, lead (Pb2+) ions have shown the highest selectivity as compared to other metal ions without any interference in the competitive ion study. The detection limit of Pb2+ ions was found to be 1.7 µM by this nanosensor. The binding ratio and stoichiometry was found to be 1:1 as measured by Job’s plot. The binding strength was also computed through Benesei-Hildebrand equation.

Keywords

iron oxide nanoparticles, p-aminobenzoic acid, Job’s plot, Chemosensors, Schiff base, Lead ions detection

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