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Dye Sensitized Solar Cell (DSSC) Fabrication Using Methanol Extract of Onion Peel as a Natural Sensitizer

Year 2022, , 1285 - 1294, 30.11.2022
https://doi.org/10.18596/jotcsa.1114611

Abstract

Methanol extracts of onion peel waste (Allium cepa) were applied as natural sensitizer in Dye-Sensitized Solar Cell (DSSC) fabrication. This research investigated the dye characteristics of onion peel extract and its power conversion efficiency. Onion peel extraction was carried out using unacidified methanol extract (UME) and acidified methanol extract (AME). Dye absorption was characterized by UV-Vis Spectrophotometer at a wavelength of 200-800 nm and FT-IR at a wave number of 4000-500 cm-1. The power conversion efficiency of the fabricated DSSC was determined by calculating the voltage and current generated by the multimeter. The red onion peel extracts, both acidified and unacidified methanol, had maximum absorption at UV-Visible range (457, 659 and 662 nm). Onion peel extract has several functional groups such as –OH, C=O, C-O-C, C=C, and C-H aromatics- showing specific absorption corresponding to the anthocyanin structure. A solar energy conversion efficiency of η= 0.0413% was obtained from UME extract with a short circuit current of up to Jsc=0.6031 mAcm-2 and a fill factor of 0.2764.

Supporting Institution

Institute for Research and Community Service (LPPM)

Project Number

No. 45/UN60/LPPM/PP/2021

Thanks

The authors sincerely thank the Institute for Research and Community Service (LPPM) Universitas Timor for making this investigation possible. This work was financially supported in accordance with the Novice Lecturer Research Program Contract No. 45/UN60/LPPM/PP/2021. The authors are also grateful to the Laboratory of Faperta Universitas Timor and the Chemical Laboratory of ITB Bandung for additional help.

References

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  • 2. Mariotti N, Bonomo M, Fagiolari L, Barbero N, Gerbaldi C, Bella F, et al. Recent advances in eco-friendly and cost-effective materials towards sustainable dye-sensitized solar cells. Green Chem. 2020;22(21):7168–218.
  • 3. Heeger AJ. Semiconducting and Metallic Polymers: The Fourth Generation of Polymeric Materials. J. Phys. Chem. B. 2001;105(36):8475-8491.
  • 4. Maddah HA, Berry V, Behura SK. Biomolecular photosensitizers for dye-sensitized solar cells: Recent developments and critical insights. Renewable and Sustainable Energy Reviews. 2020 Apr;121:109678.
  • 5. Akin S. Hysteresis-Free Planar Perovskite Solar Cells with a Breakthrough Efficiency of 22% and Superior Operational Stability over 2000 h. ACS Appl Mater Interfaces. 2019 Oct 30;11(43):39998–40005.
  • 6. Akman E, Akin S. Poly(N,N′‐bis‐4‐butylphenyl‐N,N′‐bisphenyl)benzidine‐Based Interfacial Passivation Strategy Promoting Efficiency and Operational Stability of Perovskite Solar Cells in Regular Architecture. Adv Mater. 2020;9.
  • 7. Ozturk T, Akman E, Shalan AE, Akin S. Composition engineering of operationally stable CsPbI2Br perovskite solar cells with a record efficiency over 17%. Nano Energy. 2021 Sep;87:106157.
  • 8. Shalan AE, Akman E, Sadegh F, Akin S. Efficient and Stable Perovskite Solar Cells Enabled by Dicarboxylic Acid-Supported Perovskite Crystallization. J Phys Chem Lett. 2021 Jan 28;12(3):997–1004.
  • 9. Alami AH, Faraj M, Aokal K, Hawili AA, Tawalbeh M, Zhang D. Investigating Various Permutations of Copper Iodide/FeCu Tandem Materials as Electrodes for Dye-Sensitized Solar Cells with a Natural Dye. 2020;13.
  • 10. Nasyori A, Noor FA. Effect of Natural Dye Extracting Solvents on the Performance of Dye-Sensitised Solar Cells. J Phys: Conf Ser. 2021 Jun 1;1951(1):012027.
  • 11. Wang YC, Cho CP. Improved performance of dye-sensitized solar cells with patterned fluorine-doped tin oxide electrodes. Energy. 2015 Sep;89:277–82.
  • 12. Joy C. A Review- The Potential of Natural Dyes for Dye Sensitized Solar Cells. IJISRT.2017. <URL>.
  • 13. Ye M, Wen X, Wang M, Iocozzia J, Zhang N, Lin C, et al. Recent advances in dye-sensitized solar cells: from photoanodes, sensitizers and electrolytes to counter electrodes. Materials Today. 2015 Apr;18(3):155–62.
  • 14. Kim JH, Kim DH, So JH, Koo HJ. Toward Eco-Friendly Dye-Sensitized Solar Cells (DSSCs): Natural Dyes and Aqueous Electrolytes. Energies. 2021 Dec 29;15(1):219.
  • 15. Ammar AM, Mohamed HSH, Yousef MMK, Abdel-Hafez GM, Hassanien AS, Khalil ASG. Dye-Sensitized Solar Cells (DSSCs) Based on Extracted Natural Dyes. Journal of Nanomaterials. 2019 Apr 18;2019:1–10.
  • 16. Adedokun O, Titilope K, Awodugba AO. Review on Natural Dye-Sensitized Solar Cells (DSSCs). IJET. 2016 Jun 22;2(2):34.
  • 17. Ghann W, Kang H, Sheikh T, Yadav S, Chavez-Gil T, Nesbitt F, et al. Fabrication, Optimization and Characterization of Natural Dye Sensitized Solar Cell. Sci Rep. 2017 Feb;7(1):41470.
  • 18. Kelvin Alaba Aduloju. Dye sensitized solar cell using natural dyes extracted from red leave onion. Int J Phys Sci [Internet]. 2012 Jan 30 [cited 2022 Apr 25];7(5).
  • 19. Al Batty S, Al-Jubouri SM, Wali Hakami M, Sarief A, Haque SM. Innovative economic anthocyanin dye source for enhancing the performance of dye-sensitized solar cell. Journal of Taibah University for Science. 2022 Dec 31;16(1):415–22.
  • 20. Kabir F, Bhuiyan MMH, Hossain MR, Bashar H, Rahaman MS, Manir MS, et al. Improvement of efficiency of Dye Sensitized Solar Cells by optimizing the combination ratio of Natural Red and Yellow dyes. Optik. 2019 Feb;179:252–8.
  • 21. Das SK, Ganguli S, Kabir H, Khandaker JI, Ahmed F. Performance of Natural Dyes in Dye-Sensitized Solar Cell as Photosensitizer. Trans Electr Electron Mater. 2020 Feb;21(1):105–16.
  • 22. Ramanarayanan R, P. N, C.V. N, S. S. Natural dyes from red amaranth leaves as light-harvesting pigments for dye-sensitized solar cells. Materials Research Bulletin. 2017 Jun;90:156–61.
  • 23. Oancea S, Drághici O. pH and thermal stability of anthocyanin-based optimised extracts of Romanian red onion cultivars. Czech J Food Sci. 2013 May 22;31(No. 3):283–91.
  • 24. Collings DA. Anthocyanin in the Vacuole of Red Onion Epidermal Cells Quenches Other Fluorescent Molecules. Plants. 2019 Dec 12;8(12):596.
  • 25. Syafinar R, Gomesh N, Irwanto M, Fareq M, Irwan YM. Potential of Purple Cabbage, Coffee, Blueberry and Turmeric as Nature Based Dyes for Dye Sensitized Solar Cell (DSSC). Energy Procedia. 2015 Nov;79:799–807.
  • 26. Adu REY, Gelyaman G, Kabosu M. Pemanfaatan Ekstrak Antosianin dari Limbah Kulit Bawang Merah (Allium cepa) sebagai Zat Pemeka (Sensitizer) pada Dye Sensitized Solar Cell (DSSC). ALCHEMY JPenKim. 2022 Feb 9;18(1):103.
  • 27. Richhariya G, Kumar A, Tekasakul P, Gupta B. Natural dyes for dye sensitized solar cell: A review. Renewable and Sustainable Energy Reviews. 2017 Mar;69:705–18.
  • 28. Saptarini NM, Herawati IE. Extraction methods and varieties affect total anthocyanins content in acidified extract of papery skin of onion (Allium cepa L.). Drug Invention Today. 2018;10(4):4.
  • 29. Ali OH, Al-sayed H, Yasin N, Afifi E. Effect of Different Extraction Methods on Stablity of Anthocyanins Extracted from Red Onion peels (Allium cepa) and Its Uses as Food Colorants. Bulletin of the National Nutrition Institute. 2016 Nov 1;47(2):1–24.
  • 30. Purbaningtias TE, Aprilia AC, Fauzi’ah L. The study of temperature and UV light effect in anthocyanin extract from dragon fruit (Hylocereus costaricensis) rind using UV-Visible spectrophotometer. In Malang, Indonesia; 2017 [cited 2022 Apr 25]. p. 020014.
  • 31. Wahyuningsih S, Wulandari L, Wartono MW, Munawaroh H, Ramelan AH. The Effect of pH and Color Stability of Anthocyanin on Food Colorant. IOP Conf Ser: Mater Sci Eng. 2017 Apr;193:012047.
  • 32. Maylinda EV, Rinadi A, Putri EA, Fadillah G, Wayuningsih S. Color Stability of Anthocyanins Copigmentation from Red Rice (Oryza sativa L.) Bran by Spectrophotometry UV-Vis. IOP Conf Ser: Mater Sci Eng. 2019 Sep 1;578(1):012001.
  • 33. Chang H, Kao MJ, Chen TL, Chen CH, Cho KC, Lai XR. Characterization of Natural Dye Extracted from Wormwood and Purple Cabbage for Dye-Sensitized Solar Cells. International Journal of Photoenergy. 2013;2013:1–8.
  • 34. Swer TL, Mukhim C, Bashir K, Chauhan K. Optimization of enzyme aided extraction of anthocyanins from Prunus nepalensis L. LWT. 2018 May;91:382–90.
  • 35. Hardeli, Zainul R, Isara LP. Preparation of Dye Sensitized Solar Cell (DSSC) using anthocyanin color dyes from jengkol shell (Pithecellobium lobatum Benth.) by the gallate acid copigmentation. J Phys: Conf Ser. 2019 Apr;1185:012021.
  • 36. Rodriguez‐Saona LE, Wrolstad RE. Extraction, Isolation, and Purification of Anthocyanins. Current Protocols in Food Analytical Chemistry [Internet]. 2001 Apr [cited 2022 Apr 25];00(1).
  • 37. Sani A, Ahmad A, Zenta F. Effect Of Metal Ion Cu (Ii) And Mg (Ii) On The Activities Antioxidant Anthocyanin Of Extract Ethanol Skin Dragon Fruit Red(Hylocereuspolyrhizus). ICA [Internet]. 2019 May 30 [cited 2021 Oct 28];11(1):11.
  • 38. Ahliha AH, Nurosyid F, Supriyanto A, Kusumaningsih T. Optical properties of anthocyanin dyes on TiO 2 as photosensitizers for application of dye-sensitized solar cell (DSSC). IOP Conf Ser: Mater Sci Eng [Internet]. 2018 Mar [cited 2021 Oct 28];333:012018.
  • 39. Chang H, Kao MJ, Chen TL, Chen CH, Cho KC, Lai XR. Characterization of Natural Dye Extracted from Wormwood and Purple Cabbage for Dye-Sensitized Solar Cells. International Journal of Photoenergy [Internet]. 2013 [cited 2021 Oct 28];2013:1–8.
  • 40. Favaro L, Balcão V, Rocha L, Silva E, Oliveira Jr. J, Vila M, et al. Physicochemical Characterization of a Crude Anthocyanin Extract from the Fruits of Jussara (Euterpe edulis Martius): Potential for Food and Pharmaceutical Applications. J Braz Chem Soc [Internet]. 2018 [cited 2021 Oct 28];
  • 41. Wahyuningsih S, Wulandari L, Wartono MW, Munawaroh H, Ramelan AH. The Effect of pH and Color Stability of Anthocyanin on Food Colorant. IOP Conf Ser: Mater Sci Eng [Internet]. 2017 Apr [cited 2021 Oct 28];193:012047.
Year 2022, , 1285 - 1294, 30.11.2022
https://doi.org/10.18596/jotcsa.1114611

Abstract

Project Number

No. 45/UN60/LPPM/PP/2021

References

  • 1. content-outlook-energi-indonesia-2019-bahasa-indonesia.pdf.
  • 2. Mariotti N, Bonomo M, Fagiolari L, Barbero N, Gerbaldi C, Bella F, et al. Recent advances in eco-friendly and cost-effective materials towards sustainable dye-sensitized solar cells. Green Chem. 2020;22(21):7168–218.
  • 3. Heeger AJ. Semiconducting and Metallic Polymers: The Fourth Generation of Polymeric Materials. J. Phys. Chem. B. 2001;105(36):8475-8491.
  • 4. Maddah HA, Berry V, Behura SK. Biomolecular photosensitizers for dye-sensitized solar cells: Recent developments and critical insights. Renewable and Sustainable Energy Reviews. 2020 Apr;121:109678.
  • 5. Akin S. Hysteresis-Free Planar Perovskite Solar Cells with a Breakthrough Efficiency of 22% and Superior Operational Stability over 2000 h. ACS Appl Mater Interfaces. 2019 Oct 30;11(43):39998–40005.
  • 6. Akman E, Akin S. Poly(N,N′‐bis‐4‐butylphenyl‐N,N′‐bisphenyl)benzidine‐Based Interfacial Passivation Strategy Promoting Efficiency and Operational Stability of Perovskite Solar Cells in Regular Architecture. Adv Mater. 2020;9.
  • 7. Ozturk T, Akman E, Shalan AE, Akin S. Composition engineering of operationally stable CsPbI2Br perovskite solar cells with a record efficiency over 17%. Nano Energy. 2021 Sep;87:106157.
  • 8. Shalan AE, Akman E, Sadegh F, Akin S. Efficient and Stable Perovskite Solar Cells Enabled by Dicarboxylic Acid-Supported Perovskite Crystallization. J Phys Chem Lett. 2021 Jan 28;12(3):997–1004.
  • 9. Alami AH, Faraj M, Aokal K, Hawili AA, Tawalbeh M, Zhang D. Investigating Various Permutations of Copper Iodide/FeCu Tandem Materials as Electrodes for Dye-Sensitized Solar Cells with a Natural Dye. 2020;13.
  • 10. Nasyori A, Noor FA. Effect of Natural Dye Extracting Solvents on the Performance of Dye-Sensitised Solar Cells. J Phys: Conf Ser. 2021 Jun 1;1951(1):012027.
  • 11. Wang YC, Cho CP. Improved performance of dye-sensitized solar cells with patterned fluorine-doped tin oxide electrodes. Energy. 2015 Sep;89:277–82.
  • 12. Joy C. A Review- The Potential of Natural Dyes for Dye Sensitized Solar Cells. IJISRT.2017. <URL>.
  • 13. Ye M, Wen X, Wang M, Iocozzia J, Zhang N, Lin C, et al. Recent advances in dye-sensitized solar cells: from photoanodes, sensitizers and electrolytes to counter electrodes. Materials Today. 2015 Apr;18(3):155–62.
  • 14. Kim JH, Kim DH, So JH, Koo HJ. Toward Eco-Friendly Dye-Sensitized Solar Cells (DSSCs): Natural Dyes and Aqueous Electrolytes. Energies. 2021 Dec 29;15(1):219.
  • 15. Ammar AM, Mohamed HSH, Yousef MMK, Abdel-Hafez GM, Hassanien AS, Khalil ASG. Dye-Sensitized Solar Cells (DSSCs) Based on Extracted Natural Dyes. Journal of Nanomaterials. 2019 Apr 18;2019:1–10.
  • 16. Adedokun O, Titilope K, Awodugba AO. Review on Natural Dye-Sensitized Solar Cells (DSSCs). IJET. 2016 Jun 22;2(2):34.
  • 17. Ghann W, Kang H, Sheikh T, Yadav S, Chavez-Gil T, Nesbitt F, et al. Fabrication, Optimization and Characterization of Natural Dye Sensitized Solar Cell. Sci Rep. 2017 Feb;7(1):41470.
  • 18. Kelvin Alaba Aduloju. Dye sensitized solar cell using natural dyes extracted from red leave onion. Int J Phys Sci [Internet]. 2012 Jan 30 [cited 2022 Apr 25];7(5).
  • 19. Al Batty S, Al-Jubouri SM, Wali Hakami M, Sarief A, Haque SM. Innovative economic anthocyanin dye source for enhancing the performance of dye-sensitized solar cell. Journal of Taibah University for Science. 2022 Dec 31;16(1):415–22.
  • 20. Kabir F, Bhuiyan MMH, Hossain MR, Bashar H, Rahaman MS, Manir MS, et al. Improvement of efficiency of Dye Sensitized Solar Cells by optimizing the combination ratio of Natural Red and Yellow dyes. Optik. 2019 Feb;179:252–8.
  • 21. Das SK, Ganguli S, Kabir H, Khandaker JI, Ahmed F. Performance of Natural Dyes in Dye-Sensitized Solar Cell as Photosensitizer. Trans Electr Electron Mater. 2020 Feb;21(1):105–16.
  • 22. Ramanarayanan R, P. N, C.V. N, S. S. Natural dyes from red amaranth leaves as light-harvesting pigments for dye-sensitized solar cells. Materials Research Bulletin. 2017 Jun;90:156–61.
  • 23. Oancea S, Drághici O. pH and thermal stability of anthocyanin-based optimised extracts of Romanian red onion cultivars. Czech J Food Sci. 2013 May 22;31(No. 3):283–91.
  • 24. Collings DA. Anthocyanin in the Vacuole of Red Onion Epidermal Cells Quenches Other Fluorescent Molecules. Plants. 2019 Dec 12;8(12):596.
  • 25. Syafinar R, Gomesh N, Irwanto M, Fareq M, Irwan YM. Potential of Purple Cabbage, Coffee, Blueberry and Turmeric as Nature Based Dyes for Dye Sensitized Solar Cell (DSSC). Energy Procedia. 2015 Nov;79:799–807.
  • 26. Adu REY, Gelyaman G, Kabosu M. Pemanfaatan Ekstrak Antosianin dari Limbah Kulit Bawang Merah (Allium cepa) sebagai Zat Pemeka (Sensitizer) pada Dye Sensitized Solar Cell (DSSC). ALCHEMY JPenKim. 2022 Feb 9;18(1):103.
  • 27. Richhariya G, Kumar A, Tekasakul P, Gupta B. Natural dyes for dye sensitized solar cell: A review. Renewable and Sustainable Energy Reviews. 2017 Mar;69:705–18.
  • 28. Saptarini NM, Herawati IE. Extraction methods and varieties affect total anthocyanins content in acidified extract of papery skin of onion (Allium cepa L.). Drug Invention Today. 2018;10(4):4.
  • 29. Ali OH, Al-sayed H, Yasin N, Afifi E. Effect of Different Extraction Methods on Stablity of Anthocyanins Extracted from Red Onion peels (Allium cepa) and Its Uses as Food Colorants. Bulletin of the National Nutrition Institute. 2016 Nov 1;47(2):1–24.
  • 30. Purbaningtias TE, Aprilia AC, Fauzi’ah L. The study of temperature and UV light effect in anthocyanin extract from dragon fruit (Hylocereus costaricensis) rind using UV-Visible spectrophotometer. In Malang, Indonesia; 2017 [cited 2022 Apr 25]. p. 020014.
  • 31. Wahyuningsih S, Wulandari L, Wartono MW, Munawaroh H, Ramelan AH. The Effect of pH and Color Stability of Anthocyanin on Food Colorant. IOP Conf Ser: Mater Sci Eng. 2017 Apr;193:012047.
  • 32. Maylinda EV, Rinadi A, Putri EA, Fadillah G, Wayuningsih S. Color Stability of Anthocyanins Copigmentation from Red Rice (Oryza sativa L.) Bran by Spectrophotometry UV-Vis. IOP Conf Ser: Mater Sci Eng. 2019 Sep 1;578(1):012001.
  • 33. Chang H, Kao MJ, Chen TL, Chen CH, Cho KC, Lai XR. Characterization of Natural Dye Extracted from Wormwood and Purple Cabbage for Dye-Sensitized Solar Cells. International Journal of Photoenergy. 2013;2013:1–8.
  • 34. Swer TL, Mukhim C, Bashir K, Chauhan K. Optimization of enzyme aided extraction of anthocyanins from Prunus nepalensis L. LWT. 2018 May;91:382–90.
  • 35. Hardeli, Zainul R, Isara LP. Preparation of Dye Sensitized Solar Cell (DSSC) using anthocyanin color dyes from jengkol shell (Pithecellobium lobatum Benth.) by the gallate acid copigmentation. J Phys: Conf Ser. 2019 Apr;1185:012021.
  • 36. Rodriguez‐Saona LE, Wrolstad RE. Extraction, Isolation, and Purification of Anthocyanins. Current Protocols in Food Analytical Chemistry [Internet]. 2001 Apr [cited 2022 Apr 25];00(1).
  • 37. Sani A, Ahmad A, Zenta F. Effect Of Metal Ion Cu (Ii) And Mg (Ii) On The Activities Antioxidant Anthocyanin Of Extract Ethanol Skin Dragon Fruit Red(Hylocereuspolyrhizus). ICA [Internet]. 2019 May 30 [cited 2021 Oct 28];11(1):11.
  • 38. Ahliha AH, Nurosyid F, Supriyanto A, Kusumaningsih T. Optical properties of anthocyanin dyes on TiO 2 as photosensitizers for application of dye-sensitized solar cell (DSSC). IOP Conf Ser: Mater Sci Eng [Internet]. 2018 Mar [cited 2021 Oct 28];333:012018.
  • 39. Chang H, Kao MJ, Chen TL, Chen CH, Cho KC, Lai XR. Characterization of Natural Dye Extracted from Wormwood and Purple Cabbage for Dye-Sensitized Solar Cells. International Journal of Photoenergy [Internet]. 2013 [cited 2021 Oct 28];2013:1–8.
  • 40. Favaro L, Balcão V, Rocha L, Silva E, Oliveira Jr. J, Vila M, et al. Physicochemical Characterization of a Crude Anthocyanin Extract from the Fruits of Jussara (Euterpe edulis Martius): Potential for Food and Pharmaceutical Applications. J Braz Chem Soc [Internet]. 2018 [cited 2021 Oct 28];
  • 41. Wahyuningsih S, Wulandari L, Wartono MW, Munawaroh H, Ramelan AH. The Effect of pH and Color Stability of Anthocyanin on Food Colorant. IOP Conf Ser: Mater Sci Eng [Internet]. 2017 Apr [cited 2021 Oct 28];193:012047.
There are 41 citations in total.

Details

Primary Language English
Journal Section Articles
Authors

Rısna Ernı Yatı Adu 0000-0002-8599-5478

Project Number No. 45/UN60/LPPM/PP/2021
Publication Date November 30, 2022
Submission Date May 10, 2022
Acceptance Date September 17, 2022
Published in Issue Year 2022

Cite

Vancouver Adu REY. Dye Sensitized Solar Cell (DSSC) Fabrication Using Methanol Extract of Onion Peel as a Natural Sensitizer. JOTCSA. 2022;9(4):1285-94.