Research Article
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Studies of the Properties of New Electrospun Based on PVA-PEG Polymer Systems Electrolytes for Energy Storage Devices

Year 2024, , 313 - 320, 04.02.2024
https://doi.org/10.18596/jotcsa.1262560

Abstract

Solid polymer electrolytes (SPEs) have been considerably investigated due to various electrochemical device applications. Most of the SPEs comprise polymer as a host material to provide strength and good mechanical stability and salt that transfers charge carriers to cause conductivity. Nanocomposite solid polymer electrolyte membranes based on poly(vinyl alcohol) (PVA)-poly(ethylene glycol) (PEG) blend complexed with LiClO4 and nanofillers Al2O3 at different weight percent ratios have been obtained by using electrospinning method. The conductivity and structural properties of the different systems have been characterized by using various experimental approaches such as X-ray diffraction (XRD) and Fourier transform infrared FTIR spectroscopy. The ionic conductivity of the systems has been measured by using an LCR meter in a temperature ranging from 298 to 353 K. Maximum ionic conductivity of 1.58 × 10-4 S cm-1 at room temperature has been observed for the system of PVA-PEG-LiClO4-Al2O3 (50-25-15-10) with 15 wt% weight percent of LiClO4 salt in PVA-PEG blend matrix. The ac conductivity report indicates that the ionic conductivity of the PVA-PEG-LiClO4-Al2O3 complex is influenced by the concentration of LiClO4. The effect of temperature on the ionic conductivity of polymer electrolyte complexes has been estimated by changing the temperature ranging from 298 to 353 K. However, the conductivity of the nanofiber polymer electrolyte systems increases with the rise of temperature, and the maximum conductivity of 1.58 × 10-2 S cm-1 has been recorded at 353 K. The temperature-dependent conductivity follows the Arrhenius behavior.

References

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  • 15. Shukla PK, Agrawal SL. Effect of PVAc dispersal into PVA-NH4SCN polymer electrolyte. Ionics (Kiel) [Internet]. 2000 May;6(3–4):312–20. Available from: <URL>.
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  • 19. Hashmi SA, Thakur AK, Upadhyaya HM. Experimental studies on polyethylene oxide–NaClO4 based composite polymer electrolytes dispersed with Na2SiO3. Eur Polym J [Internet]. 1998 Sep 1;34(9):1277–82. Available from: <URL>.
  • 20. Jaipal Reddy M, Sreekanth T, Subba Rao UV. Study of the plasticizer effect on a (PEO+NaYF4) polymer electrolyte and its use in an electrochemical cell. Solid State Ionics [Internet]. 1999 Nov 1;126(1–2):55–63. Available from: <URL>.
  • 21. Zhang Z, Fang S. Novel network polymer electrolytes based on polysiloxane with internal plasticizer. Electrochim Acta [Internet]. 2000 Mar 1;45(13):2131–8. Available from: <URL>.
  • 22. Pradhan DK, Samantaray BK, Choudhary RNP, Thakur AK. Effect of plasticizer on structure—property relationship in composite polymer electrolytes. J Power Sources [Internet]. 2005 Jan 4;139(1–2):384–93. Available from: <URL>.
  • 23. Pitawala HMJC, Dissanayake MAKL, Seneviratne VA, Mellander B-E, Albinson I. Effect of plasticizers (EC or PC) on the ionic conductivity and thermal properties of the (PEO)9LiTf: Al2O3 nanocomposite polymer electrolyte system. J Solid State Electrochem [Internet]. 2008 Aug 29;12(7–8):783–9. Available from: <URL>.
  • 24. Paul DR, Newman S. Polymer Blends [Internet]. Elsevier; 1978. Available from: <URL>.
  • 25. MacCallum JR, Tomlin AS, Vincent CA. An investigation of the conducting species in polymer electrolytes. Eur Polym J [Internet]. 1986 Jan 1;22(10):787–91. Available from: <URL>.
  • 26. Prajapati GK, Gupta PN. Comparative study of the electrical and dielectric properties of PVA–PEG–Al2O3–MI (M=Na, K, Ag) complex polymer electrolytes. Phys B Condens Matter [Internet]. 2011 Aug 1;406(15–16):3108–13. Available from: <URL>.
  • 27. Agrawal SL, Awadhia A. DSC and conductivity studies on PVA based proton conducting gel electrolytes. Bull Mater Sci [Internet]. 2004 Dec;27(6):523–7. Available from: <URL>.
  • 28. Finch CA. Polyvinyl alcohol, properties and applications. New York: Wiley & Sons; 1973.
  • 29. Gong K-C, Shou-Cai H. Electrical Properties of Poly(Vinyl Alcohol) Complexed with Phosphoric Acid. MRS Proc. 1988 Feb 21;135:377.
  • 30. Bhargav PB, Mohan VM, Sharma AK, Rao VVRN. Structural and electrical studies of sodium iodide doped poly(vinyl alcohol) polymer electrolyte films for their application in electrochemical cells. Ionics (Kiel) [Internet]. 2007 Aug 2;13(3):173–8. Available from: <URL>.
  • 31. Bhargav PB, Mohan VM, Sharma AK, Rao VVRN. Investigations on electrical properties of (PVA:NaF) polymer electrolytes for electrochemical cell applications. Curr Appl Phys [Internet]. 2009 Jan 1;9(1):165–71. Available from: <URL>.
  • 32. Ahmad S, Bohidar HB, Ahmad S, Agnihotry SA. Role of fumed silica on ion conduction and rheology in nanocomposite polymeric electrolytes. Polymer (Guildf) [Internet]. 2006 May 3;47(10):3583–90. Available from: <URL>.
  • 33. Min H-S, Ko J-M, Kim D-W. Preparation and characterization of porous polyacrylonitrile membranes for lithium-ion polymer batteries. J Power Sources [Internet]. 2003 Jun 1;119–121:469–72. Available from: <URL>.
  • 34. Wu G, Yang H-Y, Chen H-Z, Yuan F, Yang L-G, Wang M, et al. Novel porous polymer electrolyte based on polyacrylonitrile. Mater Chem Phys [Internet]. 2007 Aug 15;104(2–3):284–7. Available from: <URL>.
Year 2024, , 313 - 320, 04.02.2024
https://doi.org/10.18596/jotcsa.1262560

Abstract

References

  • 1. Armand MB. Polymer Electrolytes. Annu Rev Mater Res [Internet]. 1986;16:245–61. Available from: <URL>.
  • 2. MacCallum JR, Vincent CA. Polymer electrolytes reviews Elsevier. London; 1987.
  • 3. Ratner MA, Shriver DF. Ion Transport in Solvent-Free Polymers. Chem Rev [Internet]. 1988;88:109–24. Available from: <URL>.
  • 4. Bhide A, Hariharan K. Ionic transport studies on (PEO)6:NaPO3 polymer electrolyte plasticized with PEG400. Eur Polym J [Internet]. 2007 Oct 1;43(10):4253–70. Available from: <URL>.
  • 5. Gray FM. Solid polymer electrolytes : fundamentals and technological applications [Internet]. New York, NY; 1991. Available from: <URL>.
  • 6. Wieczorek W, Such K, Chung SH, Stevens JR. Comparison of Properties of Composite Polymeric Electrolytes Based on the Oxymethylene-Linked Poly (ethylene oxide) NaClO4 Electrolyte with Polyacrylamide or. alpha.-Al2O3 Additives. J Phys Chem [Internet]. 1994;98(36):9047–55. Available from: <URL>.
  • 7. Linford RG. Electrochemical Science and Technology of Polymer-I. London: Elsevier; 1987.
  • 8. Patel SK, Patel RB, Awadhia A, Chand N, Agrawal SL. Role of polyvinyl alcohol in the conductivity behaviour of polyethylene glycol-based composite gel electrolytes. Pramana [Internet]. 2007 Sep 26;69(3):467–75. Available from: <URL>.
  • 9. Scrosati B. Applications of Electroactive Polymers. London: Chapman and Hall; 1993.
  • 10. Gray FM. Fundamentals and technological applications. New York: VCH; 1991.
  • 11. Sekhon SS. Conductivity behaviour of polymer gel electrolytes: Role of polymer. Bull Mater Sci [Internet]. 2003 Apr;26(3):321–8. Available from: <URL>.
  • 12. Joykumar Singh T, Bhat SV. Morphology and conductivity studies of a new solid polymer electrolyte: (PEG)xLiClO4. Bull Mater Sci [Internet]. 2003 Dec;26(7):707–14. Available from: <URL>.
  • 13. Wieczorek W, Such K, Florjanczyk Z, Stevens JR. Polyacrylamide based composite polymeric electrolytes. Electrochim Acta [Internet]. 1995 Oct 1;40(13–14):2417–20. Available from: <URL>.
  • 14. Wieczorek W, Such / K, Florjanczyk Z, Stevens JR. Polyether, Polyacrylamide, L1CIO4 Composite Electrolytes with Enhanced Conductivity. J Phys Chem [Internet]. 1994;98:6840–50. Available from: <URL>.
  • 15. Shukla PK, Agrawal SL. Effect of PVAc dispersal into PVA-NH4SCN polymer electrolyte. Ionics (Kiel) [Internet]. 2000 May;6(3–4):312–20. Available from: <URL>.
  • 16. Rand DAJ. Battery systems for electric vehicles — a state-of-the-art review. J Power Sources [Internet]. 1979 Jan 1;4(2):101–43. Available from: <URL>.
  • 17. Rocco AM, Pereira RP, Felisberti MI. Miscibility, crystallinity and morphological behavior of binary blends of poly(ethylene oxide) and poly(methyl vinyl ether–maleic acid). Polymer (Guildf) [Internet]. 2001 Jun 1;42(12):5199–205. Available from: <URL>.
  • 18. Choi N-S, Lee Y-G, Park J-K, Ko J-M. Preparation and electrochemcial characteristics of plasticized polymer electrolytes based upon a P(VdF-co-HFP)/PVAc blend. Electrochim Acta [Internet]. 2001 Mar 15;46(10–11):1581–6. Available from: <URL>.
  • 19. Hashmi SA, Thakur AK, Upadhyaya HM. Experimental studies on polyethylene oxide–NaClO4 based composite polymer electrolytes dispersed with Na2SiO3. Eur Polym J [Internet]. 1998 Sep 1;34(9):1277–82. Available from: <URL>.
  • 20. Jaipal Reddy M, Sreekanth T, Subba Rao UV. Study of the plasticizer effect on a (PEO+NaYF4) polymer electrolyte and its use in an electrochemical cell. Solid State Ionics [Internet]. 1999 Nov 1;126(1–2):55–63. Available from: <URL>.
  • 21. Zhang Z, Fang S. Novel network polymer electrolytes based on polysiloxane with internal plasticizer. Electrochim Acta [Internet]. 2000 Mar 1;45(13):2131–8. Available from: <URL>.
  • 22. Pradhan DK, Samantaray BK, Choudhary RNP, Thakur AK. Effect of plasticizer on structure—property relationship in composite polymer electrolytes. J Power Sources [Internet]. 2005 Jan 4;139(1–2):384–93. Available from: <URL>.
  • 23. Pitawala HMJC, Dissanayake MAKL, Seneviratne VA, Mellander B-E, Albinson I. Effect of plasticizers (EC or PC) on the ionic conductivity and thermal properties of the (PEO)9LiTf: Al2O3 nanocomposite polymer electrolyte system. J Solid State Electrochem [Internet]. 2008 Aug 29;12(7–8):783–9. Available from: <URL>.
  • 24. Paul DR, Newman S. Polymer Blends [Internet]. Elsevier; 1978. Available from: <URL>.
  • 25. MacCallum JR, Tomlin AS, Vincent CA. An investigation of the conducting species in polymer electrolytes. Eur Polym J [Internet]. 1986 Jan 1;22(10):787–91. Available from: <URL>.
  • 26. Prajapati GK, Gupta PN. Comparative study of the electrical and dielectric properties of PVA–PEG–Al2O3–MI (M=Na, K, Ag) complex polymer electrolytes. Phys B Condens Matter [Internet]. 2011 Aug 1;406(15–16):3108–13. Available from: <URL>.
  • 27. Agrawal SL, Awadhia A. DSC and conductivity studies on PVA based proton conducting gel electrolytes. Bull Mater Sci [Internet]. 2004 Dec;27(6):523–7. Available from: <URL>.
  • 28. Finch CA. Polyvinyl alcohol, properties and applications. New York: Wiley & Sons; 1973.
  • 29. Gong K-C, Shou-Cai H. Electrical Properties of Poly(Vinyl Alcohol) Complexed with Phosphoric Acid. MRS Proc. 1988 Feb 21;135:377.
  • 30. Bhargav PB, Mohan VM, Sharma AK, Rao VVRN. Structural and electrical studies of sodium iodide doped poly(vinyl alcohol) polymer electrolyte films for their application in electrochemical cells. Ionics (Kiel) [Internet]. 2007 Aug 2;13(3):173–8. Available from: <URL>.
  • 31. Bhargav PB, Mohan VM, Sharma AK, Rao VVRN. Investigations on electrical properties of (PVA:NaF) polymer electrolytes for electrochemical cell applications. Curr Appl Phys [Internet]. 2009 Jan 1;9(1):165–71. Available from: <URL>.
  • 32. Ahmad S, Bohidar HB, Ahmad S, Agnihotry SA. Role of fumed silica on ion conduction and rheology in nanocomposite polymeric electrolytes. Polymer (Guildf) [Internet]. 2006 May 3;47(10):3583–90. Available from: <URL>.
  • 33. Min H-S, Ko J-M, Kim D-W. Preparation and characterization of porous polyacrylonitrile membranes for lithium-ion polymer batteries. J Power Sources [Internet]. 2003 Jun 1;119–121:469–72. Available from: <URL>.
  • 34. Wu G, Yang H-Y, Chen H-Z, Yuan F, Yang L-G, Wang M, et al. Novel porous polymer electrolyte based on polyacrylonitrile. Mater Chem Phys [Internet]. 2007 Aug 15;104(2–3):284–7. Available from: <URL>.
There are 34 citations in total.

Details

Primary Language English
Subjects Polymer Science and Technologies
Journal Section RESEARCH ARTICLES
Authors

Ramat Gul 0000-0003-3796-1406

Wan Ahmad Kamil Mahmood This is me 0000-0003-0858-4285

Publication Date February 4, 2024
Submission Date March 9, 2023
Acceptance Date November 17, 2023
Published in Issue Year 2024

Cite

Vancouver Gul R, Mahmood WAK. Studies of the Properties of New Electrospun Based on PVA-PEG Polymer Systems Electrolytes for Energy Storage Devices. JOTCSA. 2024;11(1):313-20.