Palladium(II) Complexes of Monodentate Phosphine Ligands and Their Application as Catalyst in Suzuki-Miyaura C-C Coupling Reaction at Room Temperature

Year 2018, , 895 - 902, 01.01.2018

Mustafa Kemal Yılmaz Simay İnce

https://doi.org/10.18596/jotcsa.435122

Cited By: 2

Abstract

A series of palladium(II) complexes from monodentate
phosphine ligands (1a-4a) were
successfully prepared and characterized with 1H, 31P, 13C
NMR, and HRMS techniques. These pre-catalysts were applied for the Suzuki-Miyaura C-C coupling reaction of
phenylboronic acid with bromobenzene and the influence of the base and solvent on
the performance of the pre-catalysts was investigated. Sterically hindered and
electronically deactivated aryl bromides as well as activated ones gave the
corresponding coupling products in good to excellent yields at room
temperature.

Keywords

Palladium, catalyst, phosphine, Suzuki-Miyaura C-C coupling

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