Research Article
BibTex RIS Cite

Morphological and rheological study of the epoxy polymer and their nanocomposite (NGTHTPTBAE/MDA/TSP) crosslinked by methylene dianiline and formulated by trisodium phosphate

Year 2019, , 237 - 244, 15.06.2019
https://doi.org/10.18596/jotcsa.477191

Abstract

The present work
consists the elaboration and the rheological behaviors of nanocomposite
(NGTHTPTBAE/MDA/TSP) in the presence of the epoxy resin nanoglycidyl
trihydrazine 4.4.4-tripropoxy tribisphenol A of ethylene (NGTHTPTBAE),
methylene dianiline (MDA) and trisodium phosphate (TSP) used as filler.
Furthermore, we have studied the performance of nanocomposites (NGTHTPTBAE/MDA/TSP)
crosslinked by methylene dianiline and formulated by trisodium phosphate at
different percentages. Then, the storage modulus G' and the loss modulus G''
(or tanδ = G''/G') are established as a function of the temperature. From these
dependencies, we determined the glass transition temperature or tanδ maximum.
Moreover, tan δ > 1 for liquid-like materials and it becomes lower than
unity for solid-like materials. Finally, the dispersion of the trisodium
phosphate incorporated into various prepared nanocomposite (NGTHTPTBAE/MDA/TSP)
was determined using the scanning electron microscope (SEM).

References

  • 1. Heinrich G, Kluppel M. Recent Advances in the theory of filler networking in elastomers. Adv. Polym. Sci. 2002; 160: 1-44.
  • 2. El Gouri M, Rafik M, Hegazi SE, Grich M, Meghraoui H, Elharfi A. Viscosimetry study; NMR and IR structural characterization of diglycidyl ether of bisphenol and tetraglycidyl diamino aromatic resins. Phys. Chem. New. 2010; 52: 112-128.
  • 3. Hsissou R, Bekhta A, Elharfi A. Viscosimetric and rheological studies of a new trifunctional epoxy pre-polymer with noyan ethylene: Triglycidyl Ether of Ethylene of Bisphenol A (TGEEBA). J. Mater. Environ. Sci. 2017; 8: 603-610.
  • 4. Ziraoui R, Meghraoui H, Rami N, Cherkaoui O, Choukri A, Hakam O, Elharfi A. Study of thermal degradation felaying behavior of two new tetra and hexa functional epoxy resins derivative organophosphates. Ann. Chim. Sci. Mat. 2012; 37: 85-96.
  • 5. Singha A S, Thakur VK. Mechanical properties of natural fibre reinforced polymer composites. Bull. Mater. Sci. 2008; 31: 791- 799.
  • 6. Kechaou B, Salvia M, Benzarti K, Turki C, Fakhfakh Z, Tréheux D. Role of fiber/matrix interphases on dielectric, friction and mechanical properties of glass fiber-reinforced epoxy composites. J. Compos. Mat. 2012; 46: 131-144.
  • 7. Zubarev AY, Odenbach S. Rheological properties of dense ferrofluids. Effet of chain-like aggregates. J. Magnet. Magn. Mat. 2002; 252: 241-243.
  • 8. Cassagnau P, Melis F. Rheology and processing of polymer nanocomposites. J. Polym. 2003; 44: 6607- 6615.
  • 9. Hsissou R, El Bouchti M, Elharfi A. Elaboration and Viscosimetric, Viscoelastic and Rheological Studies of a New Hexafunctional Polyepoxide Polymer: Hexaglycidyl Ethylene of Methylene Dianiline. J. Mater. Environ. Sci. 2017; 8: 4349-4361.
  • 10. Rodriguer E, Fernandez M, Eugenia M, Santamaria A. The effect of pressure on the viscosity of two different nanocomposites based on a PS matrix: A case of piezorheological complexity. J. Rheol. 2016; 60: 1199-1210.
  • 11. Hsissou R, Bekhta A, El Hilal B, El Aazaoui J, Dagdag O, Abouelouafa K, Elharfi A. Synthesis, characterization, viscosimetric study and formulation of a new nanofunctional polymer’s nanocomposite: Nanoglycidyl trihydrazine 4,4,4-tripropoxy of ethylene tribisphenol A. Inter. J. Sci. Eng. Res. 2017; 8: 1181-1188.
  • 12. Bekhta A, Elharfi A. Synthesis of novolac matrix and study of a new composite in the presence of tri-sodium phosphate. Characterization and viscosimetric study, rheological and thermal degradation. Inter. J. Innov. App. Stud. 2014; 7: 662-673.
  • 13. Hsissou R, Bekhta A, Elharfi A, Benzidia B, Hajjaji N. Theoretical and electrochemical studies of the coating behavior of a new epoxy polymer: hexaglycidyl ethylene of methylene dianiline (HGEMDA) on E24 steel 3.5 % NaCl. Portug. Electrochim. Act. 2018; 36: 101-117.
  • 14. Hsissou R, El Harfi A. Elaboration and rheological study of a new trifunctional polyepoxide macromolecular binder. J. Chem. Tech. Metall.2018; 53: 170-176.
  • 15. Hsissou R, Benzidia B, Hajjaji N, Elharfi A. Elaboration and electrochemical studies of the coating behavior of new pentafunctional epoxy polymer (pentaglycidyl ether pentabisphenol phosphorus) on E24 carbon steel in 3.5 % NaCl. J. Chem. Tech. Metall. 2018; 53: 898-905.
  • 16. Cvek M, Mrlik M, Pavlinek V. A rheological evaluation of steady shear magnetorheological flow behavior using three-parameter viscoplastic models. J. Rheol. 2016; 60: 687-694.
  • 17. Pozo O, Collin D, Finkelmann H, Roger D, Martonoty P. Gel-like elasticity in glass-forming side- chain liquid-crystal polymers. Phys. Rev. E. 2009; 80: 031801.
  • 18. Wang X, Heng S, Weiyang L, Miao D, Song Y. Complex rheological behaviors of loach (Misgurnus anguillicaudatus) skin mucus. J. Rheol. 2015; 59: 51-63.
  • 19. Hsissou R, Berradi M, El Bouchti M, Elharfi A. Synthesis characterization rheological and morphological study of a new epoxy resin pentaglycidyl ether pentaphenoxy of phosphorus and their composite (PGEPPP/MDA/PN). Poly. Bullet. 2018;doi.org/10.1007/s00289-018-2639-9.
  • 20. Bekhta A, Cherkaoui O, Elharfi A. Study of mechanical properties of a composite based on a new tetra-functional epoxy polymer formula by TGEMDA and PTS. J. Mater. Environ. Sci. 2016; 7: 3984-3992. 21. Momeni A, Joseph Filiaggi M. Rheology of polyphosphate coacervates. J. Rheol. 2016; 60: 25-34.
  • 22. Fan Z, Advani SG. Rheology of multiwall carbon nanotube suspensions. J. Rheol. 2007; 51: 585-604.
  • 23. Song Y, Zheng Q. Linear rheology of nanofilled polymers. J. Rheol. 2015; 59: 155-192.
  • 24. Abdennadher A, Vincent M, Budtova T. Rheological properties of molten flax- and Tencel polypropylene composites: Influence of fiber morphology and concentration. J. Rheol. 2016; 60: 191-202.
  • 25. Causin V, Marega C, Marigo A, Ferrara G, Ferraro A. Morphological and structural characterization of polypropylene/conductive graphite nanocomposites. Eur. Polym. J. 2006; 42: 3153- 3161.
  • 26. Kuilla T, Bhadra S, Yao D, Kim NH, Bose S, Hee LJ. Recent advances in graphene based polymer composites. Prog. Polym. Sci. 2010; 35: 1350-1375.
Year 2019, , 237 - 244, 15.06.2019
https://doi.org/10.18596/jotcsa.477191

Abstract

References

  • 1. Heinrich G, Kluppel M. Recent Advances in the theory of filler networking in elastomers. Adv. Polym. Sci. 2002; 160: 1-44.
  • 2. El Gouri M, Rafik M, Hegazi SE, Grich M, Meghraoui H, Elharfi A. Viscosimetry study; NMR and IR structural characterization of diglycidyl ether of bisphenol and tetraglycidyl diamino aromatic resins. Phys. Chem. New. 2010; 52: 112-128.
  • 3. Hsissou R, Bekhta A, Elharfi A. Viscosimetric and rheological studies of a new trifunctional epoxy pre-polymer with noyan ethylene: Triglycidyl Ether of Ethylene of Bisphenol A (TGEEBA). J. Mater. Environ. Sci. 2017; 8: 603-610.
  • 4. Ziraoui R, Meghraoui H, Rami N, Cherkaoui O, Choukri A, Hakam O, Elharfi A. Study of thermal degradation felaying behavior of two new tetra and hexa functional epoxy resins derivative organophosphates. Ann. Chim. Sci. Mat. 2012; 37: 85-96.
  • 5. Singha A S, Thakur VK. Mechanical properties of natural fibre reinforced polymer composites. Bull. Mater. Sci. 2008; 31: 791- 799.
  • 6. Kechaou B, Salvia M, Benzarti K, Turki C, Fakhfakh Z, Tréheux D. Role of fiber/matrix interphases on dielectric, friction and mechanical properties of glass fiber-reinforced epoxy composites. J. Compos. Mat. 2012; 46: 131-144.
  • 7. Zubarev AY, Odenbach S. Rheological properties of dense ferrofluids. Effet of chain-like aggregates. J. Magnet. Magn. Mat. 2002; 252: 241-243.
  • 8. Cassagnau P, Melis F. Rheology and processing of polymer nanocomposites. J. Polym. 2003; 44: 6607- 6615.
  • 9. Hsissou R, El Bouchti M, Elharfi A. Elaboration and Viscosimetric, Viscoelastic and Rheological Studies of a New Hexafunctional Polyepoxide Polymer: Hexaglycidyl Ethylene of Methylene Dianiline. J. Mater. Environ. Sci. 2017; 8: 4349-4361.
  • 10. Rodriguer E, Fernandez M, Eugenia M, Santamaria A. The effect of pressure on the viscosity of two different nanocomposites based on a PS matrix: A case of piezorheological complexity. J. Rheol. 2016; 60: 1199-1210.
  • 11. Hsissou R, Bekhta A, El Hilal B, El Aazaoui J, Dagdag O, Abouelouafa K, Elharfi A. Synthesis, characterization, viscosimetric study and formulation of a new nanofunctional polymer’s nanocomposite: Nanoglycidyl trihydrazine 4,4,4-tripropoxy of ethylene tribisphenol A. Inter. J. Sci. Eng. Res. 2017; 8: 1181-1188.
  • 12. Bekhta A, Elharfi A. Synthesis of novolac matrix and study of a new composite in the presence of tri-sodium phosphate. Characterization and viscosimetric study, rheological and thermal degradation. Inter. J. Innov. App. Stud. 2014; 7: 662-673.
  • 13. Hsissou R, Bekhta A, Elharfi A, Benzidia B, Hajjaji N. Theoretical and electrochemical studies of the coating behavior of a new epoxy polymer: hexaglycidyl ethylene of methylene dianiline (HGEMDA) on E24 steel 3.5 % NaCl. Portug. Electrochim. Act. 2018; 36: 101-117.
  • 14. Hsissou R, El Harfi A. Elaboration and rheological study of a new trifunctional polyepoxide macromolecular binder. J. Chem. Tech. Metall.2018; 53: 170-176.
  • 15. Hsissou R, Benzidia B, Hajjaji N, Elharfi A. Elaboration and electrochemical studies of the coating behavior of new pentafunctional epoxy polymer (pentaglycidyl ether pentabisphenol phosphorus) on E24 carbon steel in 3.5 % NaCl. J. Chem. Tech. Metall. 2018; 53: 898-905.
  • 16. Cvek M, Mrlik M, Pavlinek V. A rheological evaluation of steady shear magnetorheological flow behavior using three-parameter viscoplastic models. J. Rheol. 2016; 60: 687-694.
  • 17. Pozo O, Collin D, Finkelmann H, Roger D, Martonoty P. Gel-like elasticity in glass-forming side- chain liquid-crystal polymers. Phys. Rev. E. 2009; 80: 031801.
  • 18. Wang X, Heng S, Weiyang L, Miao D, Song Y. Complex rheological behaviors of loach (Misgurnus anguillicaudatus) skin mucus. J. Rheol. 2015; 59: 51-63.
  • 19. Hsissou R, Berradi M, El Bouchti M, Elharfi A. Synthesis characterization rheological and morphological study of a new epoxy resin pentaglycidyl ether pentaphenoxy of phosphorus and their composite (PGEPPP/MDA/PN). Poly. Bullet. 2018;doi.org/10.1007/s00289-018-2639-9.
  • 20. Bekhta A, Cherkaoui O, Elharfi A. Study of mechanical properties of a composite based on a new tetra-functional epoxy polymer formula by TGEMDA and PTS. J. Mater. Environ. Sci. 2016; 7: 3984-3992. 21. Momeni A, Joseph Filiaggi M. Rheology of polyphosphate coacervates. J. Rheol. 2016; 60: 25-34.
  • 22. Fan Z, Advani SG. Rheology of multiwall carbon nanotube suspensions. J. Rheol. 2007; 51: 585-604.
  • 23. Song Y, Zheng Q. Linear rheology of nanofilled polymers. J. Rheol. 2015; 59: 155-192.
  • 24. Abdennadher A, Vincent M, Budtova T. Rheological properties of molten flax- and Tencel polypropylene composites: Influence of fiber morphology and concentration. J. Rheol. 2016; 60: 191-202.
  • 25. Causin V, Marega C, Marigo A, Ferrara G, Ferraro A. Morphological and structural characterization of polypropylene/conductive graphite nanocomposites. Eur. Polym. J. 2006; 42: 3153- 3161.
  • 26. Kuilla T, Bhadra S, Yao D, Kim NH, Bose S, Hee LJ. Recent advances in graphene based polymer composites. Prog. Polym. Sci. 2010; 35: 1350-1375.
There are 25 citations in total.

Details

Primary Language English
Subjects Polymer Science and Technologies
Journal Section Articles
Authors

Rachid Hsissou 0000-0003-3080-5021

Mohamed Berradi This is me 0000-0003-1748-952X

Mehdi El Bouchti This is me 0000-0001-8788-490X

Ahmed El Harfi This is me 0000-0002-6058-2191

Publication Date June 15, 2019
Submission Date November 1, 2018
Acceptance Date May 15, 2019
Published in Issue Year 2019

Cite

Vancouver Hsissou R, Berradi M, El Bouchti M, El Harfi A. Morphological and rheological study of the epoxy polymer and their nanocomposite (NGTHTPTBAE/MDA/TSP) crosslinked by methylene dianiline and formulated by trisodium phosphate. JOTCSA. 2019;6(2):237-44.