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Activated Plantain Peel Biochar As Adsorbent For Removal of Zinc(II) Ions From Aqueous Solution: Equilibrium and Kinetics Studies.

Year 2018, Volume: 5 Issue: 3, 1257 - 1270, 01.09.2018
https://doi.org/10.18596/jotcsa.438332

Abstract

 Plantain peel biomass was carbonized, activated, and characterized using BET surface area and XRD. The XRD diffraction indicated crystalline structure with crystallite size of 14.56 nm evaluated through Debye-Scherrer equation. The pore size (cc/g) and pore surface area (m2/g) of the biochar was 8.79 and 16.69 respectively from BET surface area. Various parametric properties such as effect of initial metal ion concentration, pH, and contact time were studied in a batch reaction process. Adsorption of zinc from aqueous solution decreased with an increase of pH and initial concentration. Equilibrium modeling studies suggested that the data fitted mainly to the Langmuir isotherm. Adsorption kinetic data tested using various kinetic models fitted the Bangham’s pore diffusion model implicating pore diffusion as the main rate limiting step. The sorption studies indicated the potential of plantain peel biochar as an effective, efficient and low cost adsorbent for remediating zinc (II) ions contaminated environment.





References

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  • 2. Onyebado CO, Iyagba ET, Offor OJ. Solid soap production using plantain peels ash as source of alkali. Journal of Applied Science and Environmental Management.2004; 6: 73-7.
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  • 5. Betiku E, Sheriff O A. Modeling and optimization of Thevetiaperuviana (yellow oleander) oil biodiesel synthetic via Musa paradisiacal (plantain) peels as heterogeneous base catalyst: A case of artificial neural network vs. response surface methodology. Ind. crop. prod. 2014; 53: 314-22.
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  • 8. Parizanganeh AH, Bijnavand V, Zamani AA, Hajabolfath A. Concentration, distribution and comparison of total and bioavailable trace metals in top soils of Bonab district in Zanjan province. Open J. Soil Sci. 2012; 2: 123-32.
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  • 13. Tiwari LD, Lee S. Activated carbon and manganese coated activated carbon precursor to dead biomass in the remediation of arsenic contaminated water. Environmental Engineering Research. 2012; 17:541-8.
  • 14. Prasad AS. Zinc deficiency by global health organization. British Medical Journal. 2003; 326 (7386): 409-10.
  • 15. Jindapon W, Jaiyen S, Ngamcharussrivichai C. Al2O3-supported Mixed Ca and Zn Compounds Prepared from Waste Seashells for Synthesis of Palm Fatty Acid Methyl Esters, Chemical Engineering Communications. 2015; 202: 1591–9.
  • 16. Morin TJ, Chengeto SW, Makura V, Tatlock HM, Lindeman SV, Bennett B, Long GJ, Grandjean F, Gardinier JR. Pyrazolylmethyls prescribe the electronic properties of iron(II) tetra(pyrazolyl)lutidine chloride complexes, Dalton Trans. 2011; 40: 8024–34.
  • 17. Zhou Y, Gao B, Zimmerman AR, Cao X. Biochar-supported zerovalent iron reclaims silver from aqueous solution to form antimicrobial nanocomposite. Chemosphere. 2014; 117: 801-5.
  • 18. Demirbas A. Effects of temperature and particle size on biochar yield from pyrolysis of agricultural residues. Journal of Analytical and Applied Pyrolysis. 2003; 72: 243-8.
  • 19. Thavamani SS, Rajkumar R. Removal of Cr(II), Pb(II) and Ni(II) from aqueous solution by adsorption on alumina. Res. J. Chem. Sci. 2013; 3(8): 44-8.
  • 20. Okareh OT, Adeolu AT. Removal of Lead ion from industrial effluent using plantain wastes. Br. J. App. Sci. Technol. 2015; 8(3): 267-276.
  • 21. Cao XD, Ma L, Gao B, Harris W. Dairy manure derived biochar effectively sorbs lead and atrazine. Environ. Sci. Technol. 2009; 43(9): 3285-91.
  • 22. Mazhar IK, Saima QM, Sajida P, Muhammed YK. Citrus paradise: An effective bio-adsorbent for arsenic(V) remediation. Pak. J. Anal. Environ. Chem. 2014; 15(1): 35-41.
  • 23. Farouq R, Yousef NS. Equilibrium and Kinetics Studies of Adsorption of Copper (II) Ions on Natural Biosorbent. Int. J. Chem. Eng. Appl. 2015; 6: 319-24.
  • 24. Chakrapani CH, SureshBabu CH, Vani KNK, Somasekhara Rao K. Adsorption kinetics for the removal of fluoride from aqueous solution by activated carbon adsorbents derived from the peels of selected citrus fruits.. E- journal of chemistry. 2010; 7(SI): S419-27.
  • 25. Antonija k, Natlija V, Dam H, Davor K. Lignocellulosic materials as dye adsorbents: Adsorption of methylene blue and congo red on brewers spent grain. Croat. Chim. Acta, 2018; 91: 53-64.
  • 26. Panida S, Xianshe F. Kinetic models on chromium(VI) adsorption onto carbonized oil palm kernel with potassium hydroxide activation. Intl J. Adv. Chem. Eng. Biol. Sci. 2016; 3(1): 68-75.
  • 27. Erol K. The adsorption of calmoduline via nicotinamide immobilized poly(HEMA-GMA) cryogels. JOTCSA. 2017; 4(1): 133-48.
  • 28. Yildiz A. Adsorption of Acid Red 114 onto Fe3O4 at Caffeic acid recyclable magnetic nanocomposite. JOTCSA. 2017; 4(1): 327-40.
Year 2018, Volume: 5 Issue: 3, 1257 - 1270, 01.09.2018
https://doi.org/10.18596/jotcsa.438332

Abstract

References

  • 1. Oberio HS, Vadlani P V, Saida L, Hughes J D. Ethanol production from plantain peels using statistically optimized simultaneous saccharification and fermentation process. Waste Management. 2011; 31: 1576-85.
  • 2. Onyebado CO, Iyagba ET, Offor OJ. Solid soap production using plantain peels ash as source of alkali. Journal of Applied Science and Environmental Management.2004; 6: 73-7.
  • 3. Mitani N, Jian FM. Uptake system of silicon in different plant species. J. Exp. Bot. 2005; 56 (414): 1255–61.
  • 4. Uchimiya M, Chang S, Klasson KT. Screening biochars for heavy metal retention in soil: Role of oxygen functional groups. J. Haz. Mat. 2011; 190 (1-3): 432-41.
  • 5. Betiku E, Sheriff O A. Modeling and optimization of Thevetiaperuviana (yellow oleander) oil biodiesel synthetic via Musa paradisiacal (plantain) peels as heterogeneous base catalyst: A case of artificial neural network vs. response surface methodology. Ind. crop. prod. 2014; 53: 314-22.
  • 6. Wolfe K, Wu K, Liu RH. Antioxidant activity of apple peels. J. Agric. Food Chem. 2003; 51:609-14.
  • 7. Ismail S, Khan F, Zafar- Iqbal M. Phytoremediation: Assessing tolerance of tree species against trace metal (Pb and Cd) toxicity. Pakistan J Botany. 2013; 45: 2181-6.
  • 8. Parizanganeh AH, Bijnavand V, Zamani AA, Hajabolfath A. Concentration, distribution and comparison of total and bioavailable trace metals in top soils of Bonab district in Zanjan province. Open J. Soil Sci. 2012; 2: 123-32.
  • 9. Dada AO, Ojediran JO, Olalekan AP. Sorption of Pb2+ from aqueous solution unto modified rice husk: isotherm studies. Adv Chem Phys. 2013: 1–6 (id: 842425).
  • 10. Babel S, Kurniawan TA. Low-cost adsorbents for heavy metals uptake from contaminated water: a review. J Hazard Mater. 2003; 97(1–3): 219–43.
  • 11. Komkiene J, Baltrenaite E. Biochar as adsorbent for removal of heavy metal ions [Cadmium(II), Copper (II), Lead(II), Zinc(II) from aqueous phase. Int. J. Environ. Sci. Technol. 2016; 13: 471-82.
  • 12. Inyang M, Cao B, Pullammannappallil P, Zimmerman A R. Enhanced lead sorption by biochar derived from anaerobically digested sugarcane bagasse. Sep. Sci. Technol. 2011; 46(12): 1950-6.
  • 13. Tiwari LD, Lee S. Activated carbon and manganese coated activated carbon precursor to dead biomass in the remediation of arsenic contaminated water. Environmental Engineering Research. 2012; 17:541-8.
  • 14. Prasad AS. Zinc deficiency by global health organization. British Medical Journal. 2003; 326 (7386): 409-10.
  • 15. Jindapon W, Jaiyen S, Ngamcharussrivichai C. Al2O3-supported Mixed Ca and Zn Compounds Prepared from Waste Seashells for Synthesis of Palm Fatty Acid Methyl Esters, Chemical Engineering Communications. 2015; 202: 1591–9.
  • 16. Morin TJ, Chengeto SW, Makura V, Tatlock HM, Lindeman SV, Bennett B, Long GJ, Grandjean F, Gardinier JR. Pyrazolylmethyls prescribe the electronic properties of iron(II) tetra(pyrazolyl)lutidine chloride complexes, Dalton Trans. 2011; 40: 8024–34.
  • 17. Zhou Y, Gao B, Zimmerman AR, Cao X. Biochar-supported zerovalent iron reclaims silver from aqueous solution to form antimicrobial nanocomposite. Chemosphere. 2014; 117: 801-5.
  • 18. Demirbas A. Effects of temperature and particle size on biochar yield from pyrolysis of agricultural residues. Journal of Analytical and Applied Pyrolysis. 2003; 72: 243-8.
  • 19. Thavamani SS, Rajkumar R. Removal of Cr(II), Pb(II) and Ni(II) from aqueous solution by adsorption on alumina. Res. J. Chem. Sci. 2013; 3(8): 44-8.
  • 20. Okareh OT, Adeolu AT. Removal of Lead ion from industrial effluent using plantain wastes. Br. J. App. Sci. Technol. 2015; 8(3): 267-276.
  • 21. Cao XD, Ma L, Gao B, Harris W. Dairy manure derived biochar effectively sorbs lead and atrazine. Environ. Sci. Technol. 2009; 43(9): 3285-91.
  • 22. Mazhar IK, Saima QM, Sajida P, Muhammed YK. Citrus paradise: An effective bio-adsorbent for arsenic(V) remediation. Pak. J. Anal. Environ. Chem. 2014; 15(1): 35-41.
  • 23. Farouq R, Yousef NS. Equilibrium and Kinetics Studies of Adsorption of Copper (II) Ions on Natural Biosorbent. Int. J. Chem. Eng. Appl. 2015; 6: 319-24.
  • 24. Chakrapani CH, SureshBabu CH, Vani KNK, Somasekhara Rao K. Adsorption kinetics for the removal of fluoride from aqueous solution by activated carbon adsorbents derived from the peels of selected citrus fruits.. E- journal of chemistry. 2010; 7(SI): S419-27.
  • 25. Antonija k, Natlija V, Dam H, Davor K. Lignocellulosic materials as dye adsorbents: Adsorption of methylene blue and congo red on brewers spent grain. Croat. Chim. Acta, 2018; 91: 53-64.
  • 26. Panida S, Xianshe F. Kinetic models on chromium(VI) adsorption onto carbonized oil palm kernel with potassium hydroxide activation. Intl J. Adv. Chem. Eng. Biol. Sci. 2016; 3(1): 68-75.
  • 27. Erol K. The adsorption of calmoduline via nicotinamide immobilized poly(HEMA-GMA) cryogels. JOTCSA. 2017; 4(1): 133-48.
  • 28. Yildiz A. Adsorption of Acid Red 114 onto Fe3O4 at Caffeic acid recyclable magnetic nanocomposite. JOTCSA. 2017; 4(1): 327-40.
There are 28 citations in total.

Details

Primary Language English
Subjects Chemical Engineering
Journal Section Articles
Authors

Nworie Felıx

Nwabue Ienna This is me

İkelle Ikelle This is me

Ogah Anselm This is me

Elom Nwabueze This is me

İtumoh Emeka This is me

Oroke Clinton This is me

Publication Date September 1, 2018
Submission Date June 28, 2018
Acceptance Date October 30, 2018
Published in Issue Year 2018 Volume: 5 Issue: 3

Cite

Vancouver Felıx N, Ienna N, Ikelle İ, Anselm O, Nwabueze E, Emeka İ, Clinton O. Activated Plantain Peel Biochar As Adsorbent For Removal of Zinc(II) Ions From Aqueous Solution: Equilibrium and Kinetics Studies. JOTCSA. 2018;5(3):1257-70.

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