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Sulu çözeltiden Cu(II) iyonlarının uzaklaştırılması için çay fabrikası atıklarından üretilen düşük maliyetli yeni bir aktif karbon: Denge, kinetik ve termodinamik değerlendirme

Year 2018, Issue: 2, 1 - 10, 30.06.2018

Abstract

Bu çalışmada, siyah çay
üretimi esnasında ortaya çıkan atıklardan sülfürik asit kullanarak kimyasal
aktivasyonla yeni bir aktif karbon üretildi ve sulu çözeltiden Cu(II)
iyonlarının uzaklaştırılması için adsorpsiyon performansı test edildi. Yüksek
maliyetli bir inert atmosfer-karbonizasyon fırınına ihtiyaç duyulmadan sadece
basit bir laboratuvar fırını kullanarak yüksek adsorpsiyon kapasiteli ve düşük
maliyetli bir aktif karbon üretildi. Sulu çözeltiden Cu(II) iyonlarının aktif
karbon üzerinde adsorpsiyonu denge, kinetik ve termodinamik açıdan incelendi.
Çalkalama modunda yapılan adsorpsiyon testlerinden sonra başlangıç çözelti
pH’sı 5.0’a ve çalkalama süresi 4.0 saate optimize edildi. Aktif karbon
üzerinde Cu(II) iyonlarının adsorpsiyon kinetiği yalancı ikinci mertebeden
kinetik modele uyduğu ve Freundlich izoterm modelinin de adsorpsiyon
verileriyle daha uyumlu olduğu tespit edildi. Doğrusal Langmuir izoterm
modelinden aktif karbonun Cu(II) adsorpsiyon kapasitesinin 28.30 mg g–1 olduğu
ve sıcaklığın 5 o C’den 40 o C’ye yükselmesiyle adsorpsiyon kapasitesinin
neredeyse %50 oranında arttığı belirlendi. Bu sonuçlardan, her hangi bir alanda
kullanılmayan ve çevreye atık olarak boşaltılan çay endüstrisi atıklarından
neredeyse sıfır maliyetle üretilen aktif karbonun, sulu çözeltiden Cu(II)
iyonlarını yüksek performansla uzaklaştırabileceği kanıtlandı.

References

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Demiral, H. and Güngor, C., Adsorption of copper(II) from aqueous solutions on activated carbon prepared from grape bagasse, J. Clean. Prod. 2016, 124, 103–113. 14. Shou, J. and Qiu, M., Adsorption of copper ions onto activated carbon from capsicum straw, Desalin. Water Treat. 2016, 57, 353–359. 15. Soylak, M., Acar, D. and Alothman, Z. A., Activated carbon cloth (ACC) as efficient adsorbent for trace Cu(II), Co(II), Cd(II), Pb(II), Mn(II), and Ni(II) as 0-0-diethylphosphorodithioic acid chelates for the enrichment from water and soil samples, Atom. Spectros. 2017, 38, 65–70. 16. Guardia M. and Garrigues, S., Handbook of mineral elements in food, John Wiley & Sons, Ltd., 2015. 17. Sarı, A., Tuzen, M., Cıtak, D. and Soylak, M., Adsorption characteristics of Cu(II) and Pb(II) onto expanded perlite from aqueous solution, J. Hazard. Mater. 2007, 148, 387–394. 18. Gündoğan, R., Acemioğlu, B. and Alma, M. H., Copper(II) adsorption from aqueous solution by herbaceous peat, J. Colloid Interface Sci. 2004, 269, 303–309. 19. Lata, H., Garg, V. K. and Gupta, R. K., Adsorptive removal of basic dye by chemically activated parthenium biomass: equilibrium and kinetic modeling, Desalination 2008, 219, 250–261. 20. Lata, H., Garg, V. K. and Gupta, R. K., Sequestration of nickel from aqueous solution onto activated carbon prepared from Parthenium hysterophorus L., J. Hazard. Mater. 2008, 157, 503–509. 21. Singh, C.K., Sahu, J. N., Mahalik, K. K., Mohanty, C. R., Mohan, B. R. and Meikap, B. C., Studies on the removal of Pb(II) from wastewater by activated carbon developed from Tamarind Wood activated with sulphuric acid, J. Hazard. Mater. 2008, 153, 221–228. 22. Lagergren, S., About the theory of so-called adsorption of soluble substance, Kungliga Svenska Veterskopsakademiens Handlinga, 1898, 24, 1–39. 23. Yavuz, Ö., Altunkaynak, Y. and Güzel, F., Removal of copper, nickel, cobalt and manganese from aqueous solution by kaolinite, Water Res. 2003, 37, 948–952. 24. 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A new low-cost activated carbon produced from tea-industry waste for removal of Cu(II) ions from aqueous solution: Equilibrium, kinetic and thermodynamic evaluation

Year 2018, Issue: 2, 1 - 10, 30.06.2018

Abstract

In this study, a new activated carbon was produced by
chemical activation using H2SO4 from the wastes generated
during black tea production, and after characterization by various parameters,
its adsorption performance was tested for removal of Cu(II) ions from aqueous
solution. A low-cost activated carbon with high adsorption capacity was
produced using only an oven without needing a high cost inert atmosphere-carbonization
furnace. Characterization of the produced activated carbon was performed by
parameters such as proximate ultimate analyzes, BET surface area, SEM images,
FT-IR spectra. The adsorption of Cu(II) ions from aqueous solution on the activated
carbon was investigated in terms of equilibrium, kinetics and thermodynamics. After
the batch mode adsorption tests, the initial pH was optimized to 5.0 and the
agitation time to 4.0 hours. The adsorption kinetics of Cu(II) ions on
activated carbon were fitted with the psedudo-second order kinetic model, and
the Freundlich isotherm model was more compatible with experimental data. It
was determined that Cu(II) adsorption capacity of the activated carbon was
28.30 mg/g, and the adsorption capacity was increased by almost 50% by
increasing the temperature from 5 to 40 oC. From the results, it has
been proven that activated carbon produced from tea-industry waste, which have
no use area and left as waste to the environment, at almost zero cost can
remove Cu(II) ions from wastewaters with very high performance. 

References

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Duran, C., Ozdes, D., Gundogdu, A., Imamoglu, M. and Senturk, H. B., Tea industry waste activated carbon, as a novel adsorbent, for separation, preconcentration and speciation of chromium, Anal. Chim Acta 2011, 688, 75–83. 10. Hayashi, J., Horikawa, T., Takeda, I., Muroyama, K. and Ani, F. N., Preparing activated carbon from various nutshells by chemical activation with K2CO3, Carbon 2002, 40, 2381–2386. 11. Gao, X., Wu, L., Xu, Q., Tian, W., Li, Z. and Kobayashi, N., Adsorption kinetics and mechanisms of copper ions on activated carbons derived from pinewood sawdust by fast H3PO4 activation, Environ. Sci. Pollut. R. 2018, in press, doi:10.1007%2Fs11356-017-1079–7. 12. Imamoglu, M., Ozturk, A., Aydın, Ş., Manzak, A., Gündoğdu, A. and Duran, C., Adsorption of Cu(II) ions from aqueous solution by hazelnut husk activated carbon prepared with potassium acetate, J. Disper. Sci. Technol. 2018, in press., doi: 10.1080/01932691.2017.1385479. 13. 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Colloid Interface Sci. 2004, 269, 303–309. 19. Lata, H., Garg, V. K. and Gupta, R. K., Adsorptive removal of basic dye by chemically activated parthenium biomass: equilibrium and kinetic modeling, Desalination 2008, 219, 250–261. 20. Lata, H., Garg, V. K. and Gupta, R. K., Sequestration of nickel from aqueous solution onto activated carbon prepared from Parthenium hysterophorus L., J. Hazard. Mater. 2008, 157, 503–509. 21. Singh, C.K., Sahu, J. N., Mahalik, K. K., Mohanty, C. R., Mohan, B. R. and Meikap, B. C., Studies on the removal of Pb(II) from wastewater by activated carbon developed from Tamarind Wood activated with sulphuric acid, J. Hazard. Mater. 2008, 153, 221–228. 22. Lagergren, S., About the theory of so-called adsorption of soluble substance, Kungliga Svenska Veterskopsakademiens Handlinga, 1898, 24, 1–39. 23. Yavuz, Ö., Altunkaynak, Y. and Güzel, F., Removal of copper, nickel, cobalt and manganese from aqueous solution by kaolinite, Water Res. 2003, 37, 948–952. 24. Ho, Y. S. and McKay, G., Kinetic models for the sorption of dye from aqueous solution by wood, J. Environ. Sci. Heal. B 1998, 76, 183–191. 25. Mall, I. D. and Srivastava, V. C., Adsorptive removal of malachite green dye from aqueous solution by bagasse fly ash and activated carbon – kinetic study and equilibrium isotherm Analyses, Colloid. Surface. A 2005, 264, 17–28. 26. Kavitha, D. and Namasivayam, C., Capacity of activated carbon in the removal of acid brilliant blue: determination of equilibrium and kinetic model parameters, Chem. Eng. J. 2008, 139, 453–461. 27. Gupta, G. S., Prasad, G. and Singh, V. N., Removal of chrome dye from aqueous solutions by mixed adsorbents: Fly ash and coal, Water Res. 1990, 24, 45–50. 28. Orumwense, F. F. O., Removal of lead from water by adsorption on a kaolinitic clay, J. Chem. Technol. Biotechnol. 1996, 65, 363–369. 29. Gundogdu, A., Duran, C., Senturk, H. B., Soylak, M., Ozdes, D., Serencam, H. and Imamoglu, M., Adsorption of phenol from aqueous solution on a low-cost activated carbon produced from tea-industry waste: Equilibrium, kinetic, and thermodynamic study, J. Chem. Eng. Data 2012, 57, 2733–2743. 30. Qada, E. N. E., Allen, S. J. and Walker, G. M., Adsorption of methylene blue onto activated carbon produced from steam activated bituminous coal: A study of equilibrum Adsorption isotherm, Chem. Eng. J. 2006, 124, 103–110. 31. Langmuir, I., The adsorption of gases on plane surfaces of glass, mica, and platinum, J. Am. Chem. Soc. 1918, 40, 1361–1403. 32. Adamson, A. W., Physical chemistry of surfaces, 2nd edition, New York, Interscience, 1967. 33. Freundlich, H. M. F., Über die adsorption in Lösungen, Zeitschrift für Physikalische Chemie, 1906, 57, 385–470. 34. Atkins, P. and dePaula, J., Physical chemistry, Oxford University Press, Eight edition, 2006. 35. Puziy A. M., Poddubnaya O. I., Martinez-Alonso A., Suarez Garcia F., Tascon J. M. D., Surface chemistry of phosphorus – containing carbons of lignocellulosic origin, Carbon 2005, 43, 2857–2868. 36. Mohan, D., Pittman Jr., C. U., Bricka, M., Smith, F., Yancey, B., Mohammad, J., Steele, P.H., Alexandre-Franco, M. F., Gómez- Serrano, V. and Gong, H., Sorption of arsenic, cadmium, and lead by chars produced from fast pyrolysis of wood and bark during bio-oil production, J. Colloid Interface Sci. 2007, 310, 57–73. 37. Bae Jr., C. F. and Mesmer, R. E., The hydrolysis of cations, Wiley, New York, 1976. 38. Burgess, J., Metal ions in solution, Ellis Horwood, New York, 1978. 39. Bailey, S. E., Olin, T. J., Bricka, R. M. and Adrian, D. D., A review of potentially low-cost sorbents for heavy metals, Water Res. 1999, 33, 2469–2479. 40. Rao, M. M., Rao, G. P. C., Seshaiah, K., Choudary, N. V. and Wang, M. 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There are 1 citations in total.

Details

Primary Language English
Subjects Environmental Sciences, Analytical Chemistry, Physical Chemistry, Chemical Engineering
Journal Section Research Article
Authors

Ali Gündoğdu

Hasan Basri Şentürk

Celal Duran This is me

Mustafa İmamoğlu This is me

Mustafa Soylak This is me

Publication Date June 30, 2018
Published in Issue Year 2018 Issue: 2

Cite

APA Gündoğdu, A., Şentürk, H. B., Duran, C., İmamoğlu, M., et al. (2018). A new low-cost activated carbon produced from tea-industry waste for removal of Cu(II) ions from aqueous solution: Equilibrium, kinetic and thermodynamic evaluation. Karadeniz Chemical Science and Technology(2), 1-10.
AMA Gündoğdu A, Şentürk HB, Duran C, İmamoğlu M, Soylak M. A new low-cost activated carbon produced from tea-industry waste for removal of Cu(II) ions from aqueous solution: Equilibrium, kinetic and thermodynamic evaluation. Karadeniz Chem. Sci. Tech. June 2018;(2):1-10.
Chicago Gündoğdu, Ali, Hasan Basri Şentürk, Celal Duran, Mustafa İmamoğlu, and Mustafa Soylak. “A New Low-Cost Activated Carbon Produced from Tea-Industry Waste for Removal of Cu(II) Ions from Aqueous Solution: Equilibrium, Kinetic and Thermodynamic Evaluation”. Karadeniz Chemical Science and Technology, no. 2 (June 2018): 1-10.
EndNote Gündoğdu A, Şentürk HB, Duran C, İmamoğlu M, Soylak M (June 1, 2018) A new low-cost activated carbon produced from tea-industry waste for removal of Cu(II) ions from aqueous solution: Equilibrium, kinetic and thermodynamic evaluation. Karadeniz Chemical Science and Technology 2 1–10.
IEEE A. Gündoğdu, H. B. Şentürk, C. Duran, M. İmamoğlu, and M. Soylak, “A new low-cost activated carbon produced from tea-industry waste for removal of Cu(II) ions from aqueous solution: Equilibrium, kinetic and thermodynamic evaluation”, Karadeniz Chem. Sci. Tech., no. 2, pp. 1–10, June 2018.
ISNAD Gündoğdu, Ali et al. “A New Low-Cost Activated Carbon Produced from Tea-Industry Waste for Removal of Cu(II) Ions from Aqueous Solution: Equilibrium, Kinetic and Thermodynamic Evaluation”. Karadeniz Chemical Science and Technology 2 (June 2018), 1-10.
JAMA Gündoğdu A, Şentürk HB, Duran C, İmamoğlu M, Soylak M. A new low-cost activated carbon produced from tea-industry waste for removal of Cu(II) ions from aqueous solution: Equilibrium, kinetic and thermodynamic evaluation. Karadeniz Chem. Sci. Tech. 2018;:1–10.
MLA Gündoğdu, Ali et al. “A New Low-Cost Activated Carbon Produced from Tea-Industry Waste for Removal of Cu(II) Ions from Aqueous Solution: Equilibrium, Kinetic and Thermodynamic Evaluation”. Karadeniz Chemical Science and Technology, no. 2, 2018, pp. 1-10.
Vancouver Gündoğdu A, Şentürk HB, Duran C, İmamoğlu M, Soylak M. A new low-cost activated carbon produced from tea-industry waste for removal of Cu(II) ions from aqueous solution: Equilibrium, kinetic and thermodynamic evaluation. Karadeniz Chem. Sci. Tech. 2018(2):1-10.