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Adsorption of Uranium (VI) on organic cation-moded kula volcanite and optimization with surface response method (RSM)

Year 2023, , 248 - 258, 23.11.2023
https://doi.org/10.29233/sdufeffd.1265417

Abstract

First of all, the structural characteristics of the prepared HDTMA-volcanite. such as XRF, SEM and BET surface area were examined, then uranium U(VI) adsorption from aqueous solutions was optimized by surface response method (RSM), which is widely used in industrial research. . Effective experimental conditions on adsorption efficiency: pH (3-8), time (30-150 minutes), uranium concentration (20-80 mg/L) and temperature (20-60 °C) were selected. The best possible combinations of these parameters were obtained by the surface response method (RSM). The central composite design (CCD) was chosen for the design of the experimental conditions. According to the RSM results, it was determined that the experimental design fit the quadratic model, and the R2 and R2adj values, which are the parameters showing the model fit, were 0.98 and 0.95, respectively. HDTMA-Volk at optimum conditions. Adsorption capacity was obtained as 4.41 mg/g for the HDTMA-Volcanics at optimum conditions. The compatibility of the obtained data with adsorption isotherms was investigated, and thermodynamic parameters were calculated.

References

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Organik katyonla modifiye edilen kula volkaniti üzerine uranyum (VI) adsorpsiyonu ve yüzey yanıt yöntemi (YYM) ile optimizasyonu

Year 2023, , 248 - 258, 23.11.2023
https://doi.org/10.29233/sdufeffd.1265417

Abstract

References

  • Upson, R. T., Burns, S. E. 2006. Sorption of nitroaromatic compounds to synthesized organoclays. J. Colloid Interface Sci. 297, 70–76.
  • Ryu, C. H., Yeo, S. D. 2010. Vapor phase adsorption of trichloroethane using organically modified montmorillonite. j. Ind. Eng. Chem. 377, 441-449.
  • Majdan, M., Pikus, S., Gajowiak, A., Gladysz-Plaska, A., Krzyzanowska, H., Zuk, J., Bujacka, M. 2010. Characterization of uranium(VI) sorption by organobentonite. Appl. Surf. Sci. 256-17, 5416-5421.
  • Shen, Y. H. 2004. Phenol sorption by organoclays having different charge characteristics. Colloids and Surfaces A: Physicochem. Eng. Aspects 232, 143–149.
  • Benedict B, Pigford TH, Levi HW (1981) Nuclear chemical engineering. Mc Graw-Hill, New York
  • Xie SB, Yang J, Chen C, Zhang XJ, Wang QL, Zhang C (2008) J Environ Radiact 99:126
  • U.H. Kaynar, M. Ayvacıklı, S.C. Kaynar et al., Removal of uranium(VI) from aqueous solutions on nanoporous ZnO by manufactured microwave-assisted combustion synthesis. J. Radioanal. Nucl. Chem. 299, 1469–1477 (2014).
  • US Environmental Protection Agency (1992) Integrated Risk Assessment System. Retrieval for metals, 9/14/92. Micromedeex Inc, Denver
  • Shuibo X, Chun Z, Xinghuo Z, Jing Y, Xiaojlan Z, Jingsong W (2009) J Environ Radioact 100:162
  • C. Kutahyalı, C. Cetinkaya, B. Acar M.B. Investigation of strontium sorption ont Kula volcanic using central composite design. J. Hazard. Mater. 201–202, 115–124 (2012).
  • Xi, S., Zhang, C., Xinghuo, Z., Jing, Y., Xiaojian, Z., Jingsong, W. 2009. “Removal of uranium (VI) from aqueous solution by adsorption of hematite”, J. Environ. Radioact, 100: 162-166
  • Kaynar, U.H. 2018b. “A Modeling and Optimization Study by Response Surface Methodology (RSM) on UO22+ İons Adsorption Using Nano-MgO Particles” Inorganic and Nano-Metal Chemistry, 48-3: 187-195
  • Hollriegl, V., Greiter, M., Giussani, A., Gerstmann, U., Michalke, B., Roth, P., Oeh, U. 2007. Observation of changes in urinary excretion of thorium in humans following ingestion of a therapeutic soil. J.Environ. Radioact. 95, 149–160.
  • S., Malik, A., Satya, S. 2009. Application of response surface methodology (RSM) for optimization of nutrient supplementation for Cr(VI) removal by aspergillus lentulusAML05. J.Hazard.Mater. 164, 1198–1204.
  • Cao, J., Wu, Y., Jin, Y., Yilihan, P., Huang, W. 2014. Response surface methodology approach for optimization of the removal of chromium (VI) by NH2-MCM -41. J. Taiwan Inst. Chem. Eng. 45, 860–868.
  • Bezerra, M. A., Santelli, R. E., Oliveira, E. P., Villar, L. S., Escaleira, L. A. 2008. Response surface methodology (RSM) as a tool for optimization in analytical chemistry. Talanta, 76, 965–977.
  • Helvacı, C. and Erkül F. 2001. Volcaniclastic rocks. Formation, general characteristics and classification. DEÜ, Engineering Faculty Publications, No: 285, Izmir (in Turkey),s: 93.
  • Sprynskyy, M., Kovalchuk, I., Buszewski, B., 2010. The separation of uranium ions by natural and modified diatomite from aqueous solution. J. Hazard. Mat.181, 700–707.
  • Liu, Y., Liu, Y., Cao, X., Hua, R., Wang, Y., Pang, C., Hua, M., Li, X. 2011. Biosorption studies of uranium (VI) on cross-linked chitosan: isotherm, kinetic and thermodynamic aspects. J. Radioanal. Nucl. Chem. 290(2), 231-239.
  • Zhao, D., Wang, X., Yang S. et al., 2012. Impact of water quality parameters on the sorption of U(VI) onto hematite. J. Environ. Radioact. 103, 20–29.
  • Sprynskyy, M., Kowalkowski, T., Tutu, H. et al., 2011. Adsorption performance of talc for uranium removal from aqueous solution. Chem. Eng. J. 171, 1185–1193.
  • KAYNAR, U.H., HIÇSÖNMEZ, U., ÇAM -KAYNAR, S., KOÇAK, S. 2018. Sorption of uranium (VI) from aqueous solutions by DEEA- organovolcanic: Isotherms and thermodynamic studies, Nucl. Sci. Techn. 29:30,
  • Zhang, Z., Zhou, Y., Liu, Y. H., Cao, X. H., Zhou, Z. W., Han, B., Liang, P., Xiong, G. 2014. Removal of thorium from aqueous solution by ordered mesoporous carbon CMK-3. J. Radioanal. Nucl. Chem., 302(1), 9–16.
  • Ilaiyaraja, P., Deb, A.K.S., Sivasubramanian, K., Ponraju, D., Venkatraman, B. 2013. Removal of thorium from aqueous solution by adsorption using PAMAM dendron- functionalized styrene divinyl benzene, J. Radioanal. Nucl. Chem. 297, 59–69.
There are 24 citations in total.

Details

Primary Language English
Subjects Inorganic Chemistry
Journal Section Makaleler
Authors

Ümit Hüseyin Kaynar 0000-0002-3321-0341

Publication Date November 23, 2023
Published in Issue Year 2023

Cite

IEEE Ü. H. Kaynar, “Adsorption of Uranium (VI) on organic cation-moded kula volcanite and optimization with surface response method (RSM)”, Süleyman Demirel University Faculty of Arts and Science Journal of Science, vol. 18, no. 3, pp. 248–258, 2023, doi: 10.29233/sdufeffd.1265417.