Year 2017, Volume 27 , Issue 3, Pages 283 - 288 2017-09-30

SENTETİK ATIK SULARDAN BOYAR MADDELERİN KİTOSAN, ÇAPRAZ BAĞLI KİTOSAN VE KİTOSAN-POLİ (AKRİLİK ASİT) KONJUGATI İLE GİDERİLMESİ
DYESTUFFS REMOVAL FROM SYNTHETIC WASTEWATER WITH CHITOSAN, CROSS-LINKED CHITOSAN AND CHITOSAN-POLY (ACRYLIC ACID) CONJUGATE

Mithat ÇELEBİ [1] , Zafer Ömer ÖZDEMİR [2]


Remazol Brillant Blue R (RBBR) ve Naphtol Blue Black (NBB) boyar maddeleri tekstil endüstrisinde yaygın olarak kullanılmaktadır. Bu çalışmada, RBBR ve NBB boyar maddeleri kitosan, çapraz bağlı kitosan ve kitosan-poli(akrilik asit) (PAA) konjugatı ile giderildi. Çapraz bağlı kitosan ve kitosan-poli(akrilik asit) konjugatı mikrodalga enerjisi kullanarak sırasıyla 15 ve 30 dakikada sentezlendi. RBBR boyar maddesi kitosan-poli(akrilik asit) konjugatı ile pH: 4.0 ve pH: 5.0’te sırasıyla % 70.23 ve % 80.78 giderildi. NBB ve RBBR çapraz bağlı kitosan ile kitosan-poli(akrilik asit) konjugatına göre daha yüksek bir yüzde ile giderildi. NBB ve RBBR boyar maddeleri kitosan ve çapraz bağlı kitosan kullanılarak yaklaşık olarak % 100 boya giderme yüzdesi ile başarılı bir şekilde giderildi. 

Remazol Brillant Blue R (RBBR) and Naphthol Blue Black (NBB) dyestuffs are commonly utilized in the textile industry. In this study, RBBR and NBB dyestuffs were removed with chitosan, cross-linked chitosan and chitosan-poly(acrylic acid) (PAA) conjugate. Cross-linked chitosan and chitosan-poly(acrylic acid) conjugate were synthesized at 15 and 30 minutes respectively by using microwave energy. RBBR dyestuff was removed 70.23 % and 80.78 % at pH: 4.0 and pH: 5.0 respectively by chitosan-poly(acrylic acid) conjugate. NBB and RBBR were removed higher percent with crosslinked chitosan than chitosan-poly(acrylic acid) conjugate at acidic pHs. NBB and RBBR were removed successfully with approximately 100 % dye removal percentage using both chitosan and cross-linked chitosan. 

  • 1. Yaman, Y.C, Gündüz, G., Kumbasar, E.P.A., 2010, "The treatment of waste water of dyeing by fenton oxidation in presence and absence of ultrasound", Tekstil ve Konfeksiyon. 20, pp. 348–358.
  • 2. Eren H.A., Yildiz, D., Demir, C., Şahin, S., 2013, "Color removal of disperse blue dyes by ozonation", Tekstil ve Konfeksiyon. 23, pp. 267–272.
  • 3. Karatas, M., Dursun, S., Argun, M.E., 2010, "The Decolorization of Azo Dye Reactive Black 5 in a Sequential Anaerobic-Aerobic System", Ekoloji. 19, pp. 15–23.
  • 4. Yagub, M.T., Sen, T.K., Afroze, S., Ang, H.M., 2014, "Dye and its removal from aqueous solution by adsorption: A review", Advanced Colloid Interface Science. 209, pp. 172–184.
  • 5. Deveci, T., Unyayar, A., Mazmanci, M.A., 2004, "Production of Remazol Brilliant Blue R decolourising oxygenase from the culture filtrate of Funalia trogii ATCC 200800", Journal of Molecular Catalysis. B Enzyme, 30, pp. 25–32.
  • 6. Onder, S., Celebi, M., Altikatoglu, M., Hatipoglu, A., Kuzu, H., 2011, "Decolorization of naphthol blue black using the horseradish peroxidase", Applied Biochemistry and Biotechnology, 163, pp. 433–443.
  • 7. Song, S., Yao, J., He, Z., Qiu, J., Chen, J., 2008, "Effect of operational parameters on the decolorization of C.I. Reactive Blue 19 in aqueous solution by ozone-enhanced electrocoagulation", Journal of Hazardous Materials, 152, pp. 204–210.
  • 8. Celebi, M., Altikatoglu, M., Akdeste, Z.M., Yildirim, H., 2013, "Determination of decolorization properties of Reactive Blue 19 dye using Horseradish Peroxidase enzyme", Turkish Journal of Biochemistry, 38, pp. 200–206.
  • 9. Vakili, M., Rafatullah, M., Salamatinia, B., Abdullah, A.Z., Ibrahim, M.H., Tan, K.B., Gholami, Z., Amouzgar, P., 2014, "Application of chitosan and its derivatives as adsorbents for dye removal from water and wastewater: A review", Carbohydrate Polymers, 113, pp. 115–130.
  • 10. Guibal, E., Roussy, J., 2007, "Coagulation and flocculation of dye-containing solutions using a biopolymer (Chitosan)", Reactive and Functional Polymers, 67, pp. 33–42.
  • 11. Petzold, G., Schwarz, S., 2006, "Dye removal from solutions and sludges by using polyelectrolytes and polyelectrolyte-surfactant complexes", Seperation and Purification Technology, 51, pp. 318–324.
  • 12. Crini, G., Badot, P.M., 2008, "Application of chitosan, a natural aminopolysaccharide, for dye removal from aqueous solutions by adsorption processes using batch studies: A review of recent literature", Progressive Polymer Science, 33, pp. 399–447.
  • 13. Yazdani, M., Bahrami, H., Arami, M., 2014, "Feldspar/titanium dioxide/chitosan as a biophotocatalyst hybrid for the removal of organic dyes from aquatic phases", Journal of Applied Polymer Science, 131, pp. 1–9.
  • 14. Jabli, M., Aloui, F., Ben Hassine, B., 2013, "[ Copper ( II )/ Cellulose-Chitosan ] Microspheres Complex for Dye Immobilization : Isotherm , Kinetic and Thermodynamic Analysis", Journal of Engineered. Fibers and Fabrics. 8, pp. 19–34.
  • 15. Chen, Y., He, F., Ren, Y., Peng, H., Huang, K., 2014, "Fabrication of chitosan/PAA multilayer onto magnetic microspheres by LbL method for removal of dyes", Journal of Chemical Engineering, 249, pp. 79–92.
  • 16. Nüchter, M., Ondruschka, B., Bonrath, W., Gum, A., 2004, "Microwave assisted synthesis - a critical technology overview", Green Chemistry, 6, pp. 128– 141.
  • 17. Michael, D., Mingos, P., Baghurst, D.R., 1991, "Applications of Microwave Dielectric Heating Effects to Synthetic Problems in Chemistry", Chemical Society Reviewers, 20, pp. 1-47.
  • 18. Baig, R.B.N., Varma, R.S., 2012., "Alternative energy input: mechanochemical, microwave and ultrasound-assisted organic synthesis", Chemical Society Reviewers, 41, pp. 1559-1584.
  • 19. Gedye, R., Smith, F., Westaway, K., Ali, H., Baldisera, L., Laberge, L., Rousell, J., 1986, "The use of microwave ovens for rapid organic synthesis", Tetrahedron Letters. 27, pp. 279–282.
  • 20. Polshettiwar, V., Varma, R.S., 2008, "Microwave-Assisted Organic Synthesis and Transformations using Benign Reaction Media", ACS, Accounts Chemical Resources, 41, pp. 629-639.
  • 21. Jiang, X., Cai, K., Zhang, J., Shen, Y., Wang, S., Tian, X., 2011, "Synthesis of a novel water-soluble chitosan derivative for flocculated decolorization", Journal of Hazardous Materials, 185, pp. 1482–1488.
  • 22. Renault, F., Sancey, B., Badot, P.M., Crini, G., 2009, "Chitosan for coagulation/flocculation processes - An eco-friendly approach", Journal of European Polymers, 45, pp. 1337–1348.
Journal Section Articles
Authors

Author: Mithat ÇELEBİ

Author: Zafer Ömer ÖZDEMİR

Dates

Publication Date : September 30, 2017

Bibtex @research article { tekstilvekonfeksiyon340946, journal = {Textile and Apparel}, issn = {1300-3356}, eissn = {2602-3075}, address = {Ege Üniversitesi Tekstil ve Konfeksiyon Araştırma Uygulama Merkezi 35100 Bornova - İZMİR}, publisher = {Ege University}, year = {2017}, volume = {27}, pages = {283 - 288}, doi = {}, title = {DYESTUFFS REMOVAL FROM SYNTHETIC WASTEWATER WITH CHITOSAN, CROSS-LINKED CHITOSAN AND CHITOSAN-POLY (ACRYLIC ACID) CONJUGATE}, key = {cite}, author = {Çelebi̇, Mithat and Özdemi̇r, Zafer Ömer} }
APA Çelebi̇, M , Özdemi̇r, Z . (2017). DYESTUFFS REMOVAL FROM SYNTHETIC WASTEWATER WITH CHITOSAN, CROSS-LINKED CHITOSAN AND CHITOSAN-POLY (ACRYLIC ACID) CONJUGATE . Textile and Apparel , 27 (3) , 283-288 . Retrieved from http://www.dergipark.org.tr/en/pub/tekstilvekonfeksiyon/issue/31290/340946
MLA Çelebi̇, M , Özdemi̇r, Z . "DYESTUFFS REMOVAL FROM SYNTHETIC WASTEWATER WITH CHITOSAN, CROSS-LINKED CHITOSAN AND CHITOSAN-POLY (ACRYLIC ACID) CONJUGATE" . Textile and Apparel 27 (2017 ): 283-288 <http://www.dergipark.org.tr/en/pub/tekstilvekonfeksiyon/issue/31290/340946>
Chicago Çelebi̇, M , Özdemi̇r, Z . "DYESTUFFS REMOVAL FROM SYNTHETIC WASTEWATER WITH CHITOSAN, CROSS-LINKED CHITOSAN AND CHITOSAN-POLY (ACRYLIC ACID) CONJUGATE". Textile and Apparel 27 (2017 ): 283-288
RIS TY - JOUR T1 - DYESTUFFS REMOVAL FROM SYNTHETIC WASTEWATER WITH CHITOSAN, CROSS-LINKED CHITOSAN AND CHITOSAN-POLY (ACRYLIC ACID) CONJUGATE AU - Mithat Çelebi̇ , Zafer Ömer Özdemi̇r Y1 - 2017 PY - 2017 N1 - DO - T2 - Textile and Apparel JF - Journal JO - JOR SP - 283 EP - 288 VL - 27 IS - 3 SN - 1300-3356-2602-3075 M3 - UR - Y2 - 2017 ER -
EndNote %0 Textile and Apparel DYESTUFFS REMOVAL FROM SYNTHETIC WASTEWATER WITH CHITOSAN, CROSS-LINKED CHITOSAN AND CHITOSAN-POLY (ACRYLIC ACID) CONJUGATE %A Mithat Çelebi̇ , Zafer Ömer Özdemi̇r %T DYESTUFFS REMOVAL FROM SYNTHETIC WASTEWATER WITH CHITOSAN, CROSS-LINKED CHITOSAN AND CHITOSAN-POLY (ACRYLIC ACID) CONJUGATE %D 2017 %J Textile and Apparel %P 1300-3356-2602-3075 %V 27 %N 3 %R %U
ISNAD Çelebi̇, Mithat , Özdemi̇r, Zafer Ömer . "DYESTUFFS REMOVAL FROM SYNTHETIC WASTEWATER WITH CHITOSAN, CROSS-LINKED CHITOSAN AND CHITOSAN-POLY (ACRYLIC ACID) CONJUGATE". Textile and Apparel 27 / 3 (September 2017): 283-288 .
AMA Çelebi̇ M , Özdemi̇r Z . DYESTUFFS REMOVAL FROM SYNTHETIC WASTEWATER WITH CHITOSAN, CROSS-LINKED CHITOSAN AND CHITOSAN-POLY (ACRYLIC ACID) CONJUGATE. Textile and Apparel. 2017; 27(3): 283-288.
Vancouver Çelebi̇ M , Özdemi̇r Z . DYESTUFFS REMOVAL FROM SYNTHETIC WASTEWATER WITH CHITOSAN, CROSS-LINKED CHITOSAN AND CHITOSAN-POLY (ACRYLIC ACID) CONJUGATE. Textile and Apparel. 2017; 27(3): 283-288.